Multi-Chamber Gas Sensor for Simultaneous NOx and CO2 Detection

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Solution Overview

Problem

Existing gas sensors cannot simultaneously detect the concentrations of NOx and carbon dioxide in a measurement-object gas.

Innovation Solution

A gas sensor comprising a sensor element with an oxygen-ion-conductive solid electrolyte layer, multiple pump cells, and a control apparatus that adjusts oxygen concentration to detect NOx and carbon dioxide concentrations based on measurement pump currents, and optionally water concentration, using electrochemical pumping cells to measure NOx and carbon dioxide reductions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a gas sensor uses a single measurement chamber with one electrode to detect gas concentration, then the device structure is simple, but it can only detect one type of gas concentration simultaneously

Engineering Contradiction:
Improvedetection capabilityVSAvoidsensor structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The measurement chamber is divided into multiple separate chambers (first measurement chamber for NOx detection and second measurement chamber for CO2 detection), with each chamber containing its own dedicated electrode. This segmentation allows simultaneous detection of multiple gas types while maintaining clear functional separation and measurement specificity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The sensor element is designed with multi-functionality to simultaneously detect both NOx and CO2 concentrations using the same basic electrochemical pumping mechanism. The universal design allows a single sensor to perform multiple detection functions by incorporating multiple measurement chambers with different electrode configurations.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Adaptability or versatility

If the sensor detects both NOx and CO2 concentrations simultaneously, then the measurement coverage is comprehensive, but the measurement precision for each gas may be affected by interference from the other gas

Engineering Contradiction:
Improvedetection coverageVSAvoidgas concentration accuracy
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

By separating the measurement chambers into distinct physical spaces with dedicated electrodes, the sensor eliminates cross-interference between NOx and CO2 detection. Each chamber independently processes its specific gas measurement, ensuring high precision for both gases simultaneously without signal contamination from the other gas type.

Inventive Principle:
Principle #1Segmentation

3Measurement precision

If the sensor structure includes multiple measurement chambers and pump cells, then the measurement capability is enhanced, but the device complexity increases

Engineering Contradiction:
Improveconcentration detection accuracyVSAvoidsensor configuration
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

Multiple measurement chambers and pump cells are integrated into a single unified sensor element structure. The combined design allows simultaneous NOx and CO2 detection within one compact unit, enhancing measurement capability while avoiding the need for separate sensor devices. The integrated architecture shares common components such as the solid electrolyte layer and control system.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sensor accurately detects NOx and carbon dioxide concentrations, with the ability to also measure water concentration, by controlling oxygen concentration through pump cells and electrochemical processes, enhancing measurement accuracy.

Implementation Method 1

an element body including an oxygen-ion-conductive solid electrolyte layer

Methodology Applied
Scientific EffectOxygen-ion conduction: Conduction (electrical)

Implementation Method 2

a first measurement pump cell constituted by including an first inner measurement electrode disposed in a first measurement chamber... the first measurement pump cell being configured to pump out oxygen in the first measurement chamber

Methodology Applied
Scientific EffectElectrochemical pumping: Electrolysis

Implementation Method 3

the NOx in measurement-object gas is reduced in the periphery of a measurement electrode disposed in the measurement chamber

Methodology Applied
Scientific EffectElectrochemical reduction: Reduction

Data Source

PatentUS20250264438A1Gas sensor
Publication Date: 2025.08.21 NGK INSULATORS LTD
  • US20250264438A1 patent drawing
  • US20250264438A1 patent drawing
  • US20250264438A1 patent drawing

AI summary

A gas sensor includes a sensor element including an element body, a first measurement pump cell, a second measurement pump cell, an adjustment pump cell, and a reference electrode; and a control apparatus, wherein the control apparatus detects a NOx concentration based on a first measurement pump current which flows when the oxygen produced due to reduction of NOx is pumped out, and the control apparatus detects a carbon dioxide concentration based on a second measurement pump current which flows when the oxygen produced due to reduction of carbon dioxide in a second measurement chamber is pumped out, and a change in a first measurement pump current which flows during execution of a adjustment pump control process and a first measurement pump control process when at least one of an adjustment voltage target value or a first measurement voltage target value is changed.