Multi-Compatibilizer for Waste Polymer Blends

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Solution Overview

Problem

Waste polymer mixtures in the white goods sector face challenges due to poor mechanical properties, phase separation, and material defects when different polymers with varying physical properties are processed together, leading to degradation and reduced recyclability.

Innovation Solution

A multi-compatibilizer composition comprising polypropylene (PP), a thermal stabilizer, polypropylene grafted 2-hydroxyethyl methacrylate, polypropylene grafted maleic anhydride, and maleic anhydride-grafted [styrene-b-(ethylene-co-butylene)-b-styrene] is used to harmonize waste polymers, including PP, ABS, glass fiber reinforced PP, and polycarbonate, enhancing interfacial adhesion and reducing phase separations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If waste polymers with different physical properties are processed together, then recycling and reuse are achieved, but phase separation and material defects occur leading to poor mechanical properties

Engineering Contradiction:
Improverecyclability of waste polymersVSAvoidmechanical properties of processed parts
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

Compatibilizers are introduced as intermediary substances that mediate between immiscible polymer phases. The patent employs multiple compatibilizers including polypropylene-grafted-maleic anhydride and polypropylene-grafted-2-hydroxyethyl methacrylate, which act as molecular bridges to improve interfacial adhesion between different waste polymer types, thereby preventing phase separation while maintaining mechanical integrity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite compatibilizer system combining multiple different compatibilizer types in specific ratios. This multi-component composite approach addresses the complexity of waste polymer mixtures by providing synergistic effects that enhance both interfacial adhesion and overall material performance, enabling successful recycling of diverse polymer waste streams

Inventive Principle:
Principle #40Composite materials

2Productivity

If multiple different types of polymeric materials are processed together, then material reuse is enabled, but interfacial adhesion decreases causing peeling problems

Engineering Contradiction:
Improveprocessing efficiency of waste polymersVSAvoidinterfacial adhesion between polymers
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent utilizes compatibilizers as intermediary agents that specifically target interfacial regions between immiscible polymers. These compatibilizers reduce interfacial tension and promote adhesion, enabling efficient processing of multi-component waste polymer mixtures without suffering from peeling or delamination issues

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention optimizes processing parameters including temperature control and compatibilizer concentration ratios to maintain adequate interfacial adhesion during processing. By carefully controlling these parameters, the system achieves both high productivity and maintained interfacial strength in processed composite parts

Inventive Principle:
Principle #35Parameter changes

3Productivity

If waste polymers with different melting points are processed simultaneously, then recycling efficiency is improved, but degradation of low melting point polymers occurs

Engineering Contradiction:
Improverecycling efficiency of waste polymersVSAvoidintegrity of low melting point polymers
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent incorporates thermal stabilizers in the compatibilizer formulation before processing begins. These stabilizers provide preliminary protection to heat-sensitive low melting point polymers during the heating and mixing phases, preventing degradation while allowing efficient processing of the complete waste polymer mixture

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The compatibilizer system includes components that provide beforehand cushioning against thermal oxidation and degradation. By incorporating these protective agents in advance, the system cushions the low melting point polymers from harmful thermal effects during simultaneous processing, maintaining their integrity while achieving high recycling efficiency

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-compatibilizer enables simultaneous processability of waste polymers with different melting points, increases impact strength, and allows for the reuse of waste plastic parts in injection molding processes, ensuring sustainable and environmentally friendly production of washing machine components.

Implementation Method 1

a thermal stabilizer protecting the waste polymer mixture against the degradation due to the thermal oxidation

Methodology Applied
Scientific EffectThermal oxidation: Oxidation

Implementation Method 2

Compatibilization in polymer chemistry is the addition of a substance to an immiscible blend of polymers that will increase their increase their interfacial adhesion between the immiscible plastics and reduces the blend interfacial tension

Methodology Applied
Scientific EffectInterfacial adhesion: Adhesive

Implementation Method 3

Compatibilization of the system will give rise to the a finer morphology and more homogeneous dispersion of polymers by creating interactions between the two previously immiscible polymers

Methodology Applied
Scientific EffectHomogeneous dispersion: Dispersion (of waves)

Data Source

PatentEP3924404B1A multi-compatibilizer for a waste polymer mixture and a washing machine made of the compatibilized polymer blend
Publication Date: 2023.04.12 ARCELIK AS

AI summary

This invention relates with a multi-compatibilizer composition for a waste polymer mixture and a new harmonized/compatibilized polymer blend to produce a washing machine.