Multi-Component Organic Composition for OLED Inkjet Printing

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving high luminous efficiency and long device lifetime, particularly with single-host materials and vacuum evaporation processes, which are costly and limit large-area, low-cost display applications, while solution processing methods like inkjet printing lack effective multi-host material systems and ink printability.

Innovation Solution

A multi-component composition comprising at least three organic functional materials H1, H2, and H3, with specific energy level relationships forming a type II semiconductor heterojunction, is developed, along with an organic solvent, to enhance printing and film-forming performance, thereby improving the efficiency and lifetime of OLEDs through solution processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If single-host materials are used in OLEDs, then device structure is simple, but carrier transmission rates are unbalanced causing serious efficiency roll-off at high brightness and shortened lifespan

Engineering Contradiction:
Improvehost material system complexityVSAvoiddevice efficiency stability and lifespan
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent uses a composite host material system consisting of three components: H1 (electron transport material), H2 (hole transport material), and H3 (exciplex-forming material). This multi-component composite structure balances electron and hole transmission rates, prevents efficiency roll-off at high brightness, and extends device lifespan while maintaining manageable structural complexity through systematic material selection based on energy level matching.

Inventive Principle:
Principle #40Composite materials

2Reliability

If co-host materials are used to improve efficiency and lifetime, then luminous efficiency and lifetime are greatly improved, but vacuum evaporation process requires fine masks and has high processing requirements limiting large-area applications

Engineering Contradiction:
Improvedevice efficiency and lifetimeVSAvoidprocessing complexity and cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces the mechanical vacuum evaporation process with a solution processing approach using inkjet printing. The composite host materials (H1, H2, H3) are dissolved in solvents to form printable inks that can be deposited directly onto substrates, eliminating the need for vacuum chambers and fine masks. This substitution enables large-area, low-cost manufacturing while maintaining the efficiency and lifetime benefits of co-host material systems.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent utilizes inkjet printing technology, which employs hydraulic principles to deposit material solutions onto substrates. The printable ink formulations containing composite host materials are jetted through nozzles as liquid droplets, enabling precise, maskless patterning and large-area fabrication without the complexity of vacuum evaporation equipment.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Ease of manufacture

If solution processing processes like inkjet printing are used for low-cost large-area devices, then manufacturing cost and processing complexity are reduced, but there are no effective solutions for multi-host material systems, film drying process, and ink printability

Engineering Contradiction:
Improvemanufacturing cost and scalabilityVSAvoidmulti-host material system compatibility
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The patent optimizes multiple parameters to enable solution processing of composite host materials: (1) selects solvents with appropriate boiling points and solubility characteristics for inkjet printing, (2) adjusts ink viscosity and surface tension to match printhead requirements, (3) controls film drying temperature and atmosphere to achieve proper film formation, and (4) formulates ink compositions ensuring stable suspension of multiple host materials. These parameter optimizations make the composite host material system compatible with inkjet printing while maintaining material functionality.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS12167682B2Multi-component composition
Publication Date: 2024.12.10 GUANGZHOU CHINARAY OPTOELECTRONICS MATERIALS LTD
  • US12167682B2 patent drawing
  • US12167682B2 patent drawing
  • US12167682B2 patent drawing

AI summary

A composition for manufacturing an organic electronic device includes at least three organic functional materials H1, H2, and H3, and at least one organic solvent. The organic functional materials H1 and H2 can form a type II semiconductor heterojunction structure. A LUMO value of the organic functional material H3 is greater than or equal to that of the organic functional materials H1 and H2, and a HOMO value thereof is less than or equal to that of the organic functional materials H1 and H2.