Multi-functional surfactant complexes for deep subterranean penetration

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Solution Overview

Problem

Current surfactant treatments in subterranean formations face challenges in deep penetration and stability, leading to ineffective delivery of surfactants and additives to deep rock formations, where conventional methods struggle to reach dead-end pores and maintain stability during treatment operations.

Innovation Solution

The creation and use of multi-functional surfactant complexes (MSCs) formed by mixing oppositely charged surfactants and polymeric additives at a well site using a stop-flow mixing apparatus, which are then introduced into the formation as a treatment fluid, allowing for delayed release and enhanced interaction with the formation, including the use of a low-dose pumping apparatus to mix with an aqueous base fluid.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If conventional surfactant treatments are used, then the treatment process is simple, but the penetration depth and stability in deep rock formations are insufficient

Engineering Contradiction:
Improvepenetration depthVSAvoidstability
Core Design Contradiction:
Length of moving objectVSReliability

Solution Approach 1:

The patent applies composite materials by combining surfactants with oppositely charged polymeric additives to form multi-functional surfactant complexes (MSCs). This composite structure enhances both penetration depth and stability in deep rock formations, resolving the technical contradiction between reaching deeper pores and maintaining treatment stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polymeric additive acts as an intermediary between the surfactant and the rock formation. It modifies the surfactant's interaction with the formation, enabling deeper penetration while maintaining stability through the intermediary's bridging role between the surfactant molecules and the rock matrix.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If multi-functional surfactant complexes are formed by mixing oppositely charged surfactants and polymeric additives, then penetration depth and stability are enhanced, but the device complexity increases

Engineering Contradiction:
ImprovestabilityVSAvoidmixing apparatus complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the surfactant and polymeric additive mixing functions into a single stop-flow mixing apparatus. This integration reduces device complexity by combining multiple functions into one unit while still achieving the enhanced stability and penetration depth through the formation of multi-functional surfactant complexes.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The stop-flow mixing apparatus performs preliminary mixing of the surfactant and polymeric additive solutions before they are introduced into the formation. This preliminary action ensures the complexes are formed in advance, simplifying the overall process by pre-preparing the treatment fluid rather than requiring complex in-situ mixing.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If low-dose pumping apparatus is used to transfer surfactant complexes, then the precision of surfactant delivery is improved, but the pumping complexity increases

Engineering Contradiction:
Improvesurfactant delivery precisionVSAvoidpumping apparatus complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex mechanical mixing and dosing systems with a low-dose pumping apparatus that uses controlled fluid displacement. This substitution achieves precise surfactant delivery through hydraulic principles rather than complex mechanical metering, improving delivery precision while managing device complexity through fluid dynamic control.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The MSCs enhance surfactant performance by increasing penetration depth, stability, and oil recovery, enabling treatment of deep pores and altering viscoelastic properties to improve fluid flow and contact with oil globules, thereby enhancing the effectiveness of surfactant treatments in subterranean formations.

Implementation Method 1

surfactants and polymeric additives that carry opposite charges

Methodology Applied
Scientific EffectElectrostatic attraction: Electrostatics

Implementation Method 2

low-dose pumping apparatus at the well site to transfer the one or more multi-functional surfactant complexes

Methodology Applied
Scientific EffectPumping: Pump

Implementation Method 3

using the blending apparatus to mix the one or more multi-functional surfactant complexes with an aqueous base fluid

Methodology Applied
Scientific EffectConvection: Convection

Implementation Method 4

mix the one or more multi-functional surfactant complexes with an aqueous base fluid to form a treatment fluid

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 5

introducing the treatment fluid into a well bore at the well site penetrating at least a portion of a subterranean formation

Methodology Applied
Scientific EffectPressure-driven flow: Pressure Gradient

Data Source

PatentUS9970265B2Multi-functional surfactant complexes for use in subterranean formations
Publication Date: 2018.05.15 HALLIBURTON ENERGY SERVICES INC
  • US9970265B2 patent drawing
  • US9970265B2 patent drawing
  • US9970265B2 patent drawing

AI summary

Systems and methods for creating and/or using multi-functional surfactant complexes that may enhance surfactant treatments in subterranean formations are provided. In some embodiments, the methods comprise: providing a treatment fluid comprising an aqueous base fluid and one or more multi-functional surfactant complexes that comprise at least one surfactant and at least one polymeric additive, wherein the surfactant and the polymeric additive carry opposite charges; and introducing the treatment fluid into a well bore at a well site penetrating at least a portion of a subterranean formation.