Multi-layer brazing sheet corrosion resistance gradient

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Solution Overview

Problem

Brazeable multi-layer aluminum composites used in heat exchanger systems face challenges in achieving high corrosion resistance, particularly in condenser tubing applications where exposure to corrosive environments can lead to refrigerant leakage and system failure.

Innovation Solution

A multi-layer brazing sheet with specific layer configurations, including a core layer, outer interliner layer, outer braze liner layer, and optional inner layers, composed of aluminum alloys with controlled Zn, Si, Cu, Mn, and other element content, creating a corrosion resistance gradient that provides cathodic protection and enhances the electrochemical potential, thereby delaying pit formation and extending service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional single-layer aluminum composites are used, then manufacturing simplicity is maintained, but corrosion resistance in condenser tubing applications is insufficient

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The aluminum composite is divided into multiple functional layers: a core layer (3XXX-series alloy) providing structural integrity, an outer interliner layer (1XXX or 5XXX-series alloy) providing corrosion resistance, and an outer braze liner layer (4XXX-series alloy) enabling brazing. This segmentation allows each layer to specialize in one function, achieving high corrosion resistance while maintaining manufacturability through established multi-layer bonding processes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining different aluminum alloys with complementary properties. The core layer provides strength, the interliner layer provides corrosion resistance, and the braze liner provides brazability. This composite approach creates a material system that achieves corrosion resistance levels comparable to or exceeding traditional copper while maintaining the advantages of aluminum (lightweight, cost-effective).

Inventive Principle:
Principle #40Composite materials

2Reliability

If multi-layer aluminum composites are designed with multiple layers, then corrosion resistance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmanufacturing process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The multi-layer structure is pre-fabricated as a bonded composite sheet before being formed into tubing. The layers are bonded together in advance using roll bonding or other metallurgical bonding processes, creating a ready-to-use composite material that simplifies the subsequent tube forming and brazing operations. This preliminary preparation eliminates the need for complex assembly processes during tube manufacturing.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention optimizes the thickness parameters of each layer to achieve the desired corrosion resistance while controlling manufacturing complexity. The outer interliner and braze liner layers are kept relatively thin (providing sufficient corrosion protection and brazing function), while the core layer provides the necessary structural thickness. This parameter optimization ensures that the multi-layer structure remains manufacturable with standard equipment and processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layer brazing sheet demonstrates improved corrosion resistance on the exposed air side surface, reducing the risk of refrigerant leakage and extending the service lifetime of heat exchanger tubes compared to traditional materials like copper.

Implementation Method 1

creating a corrosion resistance gradient that provides cathodic protection and enhances the electrochemical potential, thereby delaying pit formation

Methodology Applied
Scientific EffectCathodic protection:

Implementation Method 2

creating a corrosion resistance gradient that provides cathodic protection and enhances the electrochemical potential

Methodology Applied
Scientific EffectElectrochemical potential enhancement:

Data Source

PatentUS8986850B2Multi-layer brazing sheet
Publication Date: 2015.03.24 ARCONIC TECHNOLOGIES LLC
  • US8986850B2 patent drawing
  • US8986850B2 patent drawing
  • US8986850B2 patent drawing

AI summary

Various illustrative embodiments of a multi-layer brazing sheet are provided. The multi-layer brazing sheet demonstrates improved corrosion resistance on its exposed air side surface.