Multi-Material Composite Gradient Layer for Metal-Polymer Interface

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Multi-material composites with metal-polymer interfaces face challenges in crack formation and propagation due to sudden changes in material properties, leading to potential failure during tension load transfer, especially when adhesives are not used.

Innovation Solution

A method involving a gradient layer with nanoparticles is introduced, where the second polymer layer with nanoparticles is positioned between the metal and the first polymer layer, allowing nanoparticles to diffuse into the first polymer layer under increased temperature or pressure, creating a gradient layer with a higher nanoparticle concentration near the metal interface, which smooths the transition of material properties, reducing crack formation and propagation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If no adhesive is used for joining metal and polymer layers, then the complexity of the bonding process is reduced, but crack formation and propagation occur at the interface due to abrupt changes in material properties

Engineering Contradiction:
Improvebonding process complexityVSAvoidinterface reliability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent applies local quality by creating a gradient layer with spatially varying nanoparticle concentration at the metal-polymer interface. The nanoparticle concentration is highest near the metal layer and decreases toward the polymer layer, locally modifying material properties where needed to bridge the property gap between dissimilar materials without requiring adhesives throughout the entire structure.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes parameter changes by varying the nanoparticle concentration as a continuous parameter through the gradient layer thickness. This gradual parameter change smooths the abrupt transition in mechanical properties between metal and polymer, reducing stress concentrations and preventing crack formation while maintaining adhesive-free joining.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the polymer layer is globally modified with nanoparticles to increase fracture toughness, then the overall strength and stiffness improve, but the polymer becomes more brittle and may fail in certain applications

Engineering Contradiction:
Improvefracture toughnessVSAvoidmaterial ductility
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by concentrating nanoparticle modification only in the gradient layer at the metal-polymer interface rather than uniformly throughout the entire polymer layer. This localized modification increases fracture toughness where it is most needed (at the stress-prone interface) while preserving the ductility and toughness of the bulk polymer material.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent uses partial action by applying nanoparticle reinforcement only to the extent necessary at the interface region. The gradient layer contains the nanoparticles, while the remainder of the polymer layer stays unmodified, providing just enough reinforcement at the critical interface without over-reinforcing the bulk material to the point of brittleness.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively reduces the tendency for crack formation and propagation at the interface, enhancing the durability and service life of the multi-material composite by gradually adapting polymer material properties to match those of the metal, thereby preventing material failure.

Implementation Method 1

whereby nanoparticles from the second polymer layer diffuse into the first polymer layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentEP3642021B1Multi-material composite and method for producing same
Publication Date: 2021.01.06 TECHNISCHE UNIVERSITAT DRESDEN
  • EP3642021B1 patent drawingFigure 1
  • EP3642021B1 patent drawingFigure 2

AI summary

The invention relates to a method for producing a multi-material composite (4) and a multi-material composite (4). Due to the abrupt change in material properties at the interface between different materials, in particular metallic and polymeric materials, cracks often develop in multi-material composites, the service life thereby being shortened. The method according to the invention is based on a gradual adjustment of the material properties of the materials of a multi-material composite (4) at the interface. Under the influence of elevated temperature or elevated temperature and elevated pressure, a composite is formed from at least one metal layer (1), at least one fiber-reinforced or unreinforced first polymer layer (2) and at least one fiber-reinforced or unreinforced second polymer layer (3), which is formed from the polymer of the first polymer layer (2) and nanoparticles and which at least in some regions is arranged between the metal layer (1) and the first polymer layer (2), nanoparticles of the second polymer layer (3) diffusing into the first polymer layer (2) such that a gradient layer (5) is formed, in which the nanoparticle concentration decreases toward the first polymer layer (2). The multi-material composite (4) produced by means of the method according to the invention has a particularly long service life and can be used, for example, in drive shafts for the aviation industry, automotive industry or maritime industry.