Multi-material selective etching reverse tone patterning

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Solution Overview

Problem

Current photolithographic techniques face limitations in reducing feature size due to minimum pitch constraints, leading to complex and costly mask edge placement control, especially at nanometer scales, resulting in low production yields and high equipment costs.

Innovation Solution

A method involving the formation of multiple lines with different materials on a substrate, allowing for selective etching and increased critical dimensions and edge placement errors, which simplifies the patterning process and reduces costs by using a three-line structure instead of a conventional single line, enabling more precise control and easier mask edge placement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Length of moving object

If photolithography techniques are used to pattern ICs, then manufacturing capability is achieved, but minimum pitch constraints limit feature size reduction

Engineering Contradiction:
Improvefeature sizeVSAvoidminimum pitch
Core Design Contradiction:
Length of moving objectVSManufacturing precision

Solution Approach 1:

The patent segments the patterning process into multiple steps (SADP, SAQP, LELE) to achieve sub-lithographic pitch features. Instead of attempting to pattern all features in a single lithography step, the process divides the pitch into multiple segments formed through sequential self-aligned deposition and etching operations, enabling feature sizes below the conventional photolithography minimum pitch

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent transitions from two-dimensional planar patterning to three-dimensional vertical structures through self-aligned deposition of mandrels and spacers. By utilizing the vertical dimension for spacer deposition on top of lithographically formed mandrels, the process achieves pitch control that is not limited by the lateral resolution of the photolithography system

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Manufacturing precision

If multi-cut or block masks are placed over lines and spaces for device patterning, then pattern transfer is achieved, but mask edge placement control becomes more complicated and difficult

Engineering Contradiction:
Improveedge placement controlVSAvoidmask complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent employs self-aligned processes where previously formed structures automatically serve as alignment references for subsequent steps. The spacers are deposited conformally on the mandrels, and the mandrels themselves define the precise location where spacers will form, eliminating the need for separate alignment operations and reducing mask complexity

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent changes the critical dimension control parameter from mask edge placement to spacer thickness, which is controlled by conformal deposition processes. This parameter transformation shifts the precision requirement from lateral mask alignment (which is complex at small dimensions) to vertical film thickness control (which can be achieved with atomic-layer precision through ALD or CVD)

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If tight geometric requirements are imposed on masks for 7 nm node structures, then patterning precision is improved, but production yields decrease and equipment costs increase

Engineering Contradiction:
Improvepatterning precisionVSAvoidproduction yields
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent uses sacrificial mandrel structures that are temporarily formed to define the final pattern but are subsequently removed. These mandrels serve their purpose during the spacer formation process and are then eliminated, allowing the use of simpler, less expensive mask structures without compromising the precision of the final pattern

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the precision and cost-effectiveness of device patterning by increasing critical dimensions and edge placement errors, allowing for more reliable and efficient pattern transfer to the substrate, thereby improving production yields and reducing equipment expenses.

Implementation Method 1

depositing a first line on the substrate in each of a plurality of gaps

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

depositing a first line on the substrate in each of a plurality of gaps

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 3

selectively etching one of the first, second or third materials relative to the other of the materials comprising the lines

Methodology Applied
Scientific EffectPlasma: Plasma

Data Source

PatentUS9728406B2Multi materials and selective removal enabled reverse tone process
Publication Date: 2017.08.08 APPLIED MATERIALS INC
  • US9728406B2 patent drawing
  • US9728406B2 patent drawing
  • US9728406B2 patent drawing

AI summary

Embodiments described herein generally relate to methods for device patterning. In various embodiments, a plurality of protrusions and gaps are formed on a substrate, and each gap is formed between adjacent protrusions. Each protrusion includes a first line, a second line and a third line. The first and third lines include a first material, and the second lines include a second material that is different from the first material. A fourth line is deposited in each gap and the fourth line includes a third material that is different than the first and second materials. Because the first, second and third materials are different, one or more lines can be removed by selective etching while adjacent lines that are made of a different material may not be covered by a mask. The critical dimensions (CD) and the edge displacement errors (EPE) of the mask are increased.