Multi-Module Thermochemical Heat Storage Using Staged Desorption

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Solution Overview

Problem

Current thermochemical heat storage systems face challenges with low storage density at typical solar collector temperatures and undesirable chemical reactions in hygroscopic salts, which limit their effectiveness for seasonal heat storage.

Innovation Solution

A closed system with multiple thermochemical modules connected through a central tube allows for flexible vapor exchange, enabling lower desorption temperatures and higher storage densities by using one TCM module as a condenser for another, thereby reducing heat loss and material instability issues.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If hygroscopic salts are used for thermochemical heat storage, then storage density is improved (1-2 GJ/m3), but material stability deteriorates due to undesirable chemical reactions such as melting, coagulation, volume changes, scaling, corrosion, and decomposition at higher temperatures

Engineering Contradiction:
Improvestorage densityVSAvoidmaterial stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent changes the temperature parameter by using multi-stage desorption processes with progressively lower temperature stages. This allows the system to achieve high storage density with hygroscopic salts while avoiding the temperature-induced instability issues by operating below critical temperature thresholds where decomposition and other unwanted reactions occur.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent segments the single high-temperature desorption process into multiple lower-temperature stages. By dividing the desorption process into sequential stages operating at different temperature levels, the system achieves complete water removal and high storage density while maintaining material stability through controlled, gradual dehydration that prevents thermal shock and chemical degradation.

Inventive Principle:
Principle #1Segmentation

2Device complexity

If solar collectors operate at typical temperatures (90°C), then system simplicity is maintained, but storage density of thermochemical materials deteriorates (lower than potential with hygroscopic salts)

Engineering Contradiction:
Improvesystem simplicityVSAvoidstorage density
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The patent introduces dynamic, adjustable temperature control through multiple heatable stages that can operate at different temperature levels. This dynamic system allows optimization of storage density by selecting appropriate temperature stages while maintaining operational simplicity through automated control sequences that manage the complexity of multi-stage operation.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system uses the heat output from exothermic hydration reactions in later stages to provide the heating energy needed for earlier desorption stages. This self-service approach eliminates the need for external high-temperature heat sources, maintaining system simplicity while achieving high storage density through internal energy recycling across multiple stages.

Inventive Principle:
Principle #25Self-service

3Loss of energy

If desorption temperature is increased to improve storage density, then heat loss is reduced, but material instability increases due to melting, coagulation, and decomposition

Engineering Contradiction:
Improveheat lossVSAvoidmaterial stability
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent implements periodic, multi-stage desorption cycles where each stage operates at a controlled temperature level for a specific duration. This periodic action with progressive temperature staging allows sufficient heat recovery at each stage while limiting exposure time at any given temperature, thereby reducing overall heat loss without subjecting materials to prolonged high-temperature conditions that would cause decomposition.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The system maintains continuous useful action through cascading heat transfer across multiple stages, where heat released in later hydration stages continuously supplies energy to earlier desorption stages. This continuous internal heat recycling minimizes external heat loss while maintaining all stages within stable temperature ranges, avoiding material degradation.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables higher storage densities and reduced heat loss, allowing for more efficient seasonal heat storage without increasing desorption temperatures, thus enhancing the stability and efficiency of thermochemical heat storage systems.

Implementation Method 1

Na2S.1⁄2H2O+41⁄2H2O←→Na2S.5H2O+heat

Methodology Applied
Scientific EffectHydration reaction: Hydrates

Implementation Method 2

The charging process to store the energy is an endothermic reaction wherein heat is supplied to split compound AB into compounds A and B

Methodology Applied
Scientific EffectDehydration reaction: Hydrates

Implementation Method 3

the at least one water condenser and the thermochemical modules are connected so that water vapour can be exchanged individually between any two selected from the list consisting of the at least one water condenser and the at least two thermochemical modules

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

the at least one water condenser and the thermochemical modules are connected so that water vapour can be exchanged individually

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Data Source

PatentUS10323885B2System and method for thermochemical storage of energy
Publication Date: 2019.06.18 NEDERLANDSE ORG VOOR TOEGEPAST NATUURWETENSCHAPPELIJK ONDERZOEK TNO
  • US10323885B2 patent drawing
  • US10323885B2 patent drawing
  • US10323885B2 patent drawing

AI summary

The present invention discloses a closed system for thermochemical storage comprising at least one water condenser and at least two thermochemical modules, wherein a first thermochemical module comprises a first thermochemical material and a second thermochemical module comprises a second thermochemical material, and wherein the at least one water condenser and the thermochemical modules are connected so that water vapor can be exchanged individually between any two selected from the list consisting of the at least one water condenser and the at least two thermochemical modules. A method for desorption in the system according to the invention is also described. In this method, the first thermochemical module is used as a condenser to dry the second thermochemical module.