Multi-Polymer Grease Cleaning System for Low Surfactant Laundry

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The detergent industry faces challenges in reducing surfactant dosage while maintaining effective greasy stain removal, particularly with the erosion of cleaning performance due to lower surfactant levels, necessitating alternative cleaning mechanisms in laundry detergents.

Innovation Solution

The development of a multi-polymer system comprising amphiphilic alkoxylated grease cleaning polymers and either clay soil cleaning polymers or soil suspending polymers, which work together to enhance cleaning efficacy even at low surfactant concentrations, available in various forms such as granules, liquids, or gels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If surfactant dosage is reduced to lower cost and improve environmental sensitivity, then cost and environmental performance improve, but greasy stain removal capability deteriorates

Engineering Contradiction:
Improvesurfactant dosageVSAvoidgreasy stain removal capability
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The invention changes the chemical structure parameters of the cleaning agents by using alkoxylated polyalkylenimine polymers with specific ethoxylate and propoxylate group ratios. This structural modification allows the polymer to maintain grease cleaning effectiveness at lower concentrations compared to traditional surfactants

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite cleaning system by combining alkoxylated polyalkylenimine polymers with conventional surfactants. This composite approach leverages the grease-removing capability of the polymer system while maintaining the proven performance of traditional surfactants, achieving effective cleaning at reduced overall surfactant dosage

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If surfactant levels are reduced to address environmental concerns, then environmental performance improves, but overall cleaning performance deteriorates

Engineering Contradiction:
Improveenvironmental impactVSAvoidoverall cleaning performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention modifies the cleaning system by introducing polymers with specific alkoxylate group parameters (5-40 ethoxylate groups and 0-20 propoxylate groups per -NH group). These parameter changes enable the polymer to provide effective soil removal with reduced environmental impact compared to high-surfactant formulations

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The alkoxylated polyalkylenimine polymer acts as an intermediary cleaning mechanism that bridges the gap between environmental concerns and cleaning effectiveness. It provides an alternative cleaning pathway that does not rely heavily on conventional surfactants, thus reducing environmental impact while maintaining cleaning performance

Inventive Principle:
Principle #24Intermediary (Mediator)

3Quantity of substance

If polymer systems are introduced to replace surfactants, then surfactant dosage can be reduced, but system complexity increases

Engineering Contradiction:
Improvesurfactant concentrationVSAvoidformulation complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The invention segments the cleaning function by dividing it between two distinct components: alkoxylated polyalkylenimine polymers for grease removal and conventional surfactants for general cleaning. This segmentation allows each component to be optimized for its specific function while working together in a simplified formulation framework

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This polymer system effectively removes grease and suspends soils, maintaining cleaning performance across a broad range of soils and stains, even with reduced surfactant levels, ensuring effective laundry detergents in various formulations.

Implementation Method 1

Like surfactants, polymers may be useful as releases of soil from fabric. The amphiphilic alkoxylated grease cleaning polymer comprises a core structure and a plurality of alkoxylate groups

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

some polymers provide for suspension of soils dispersed in the wash liquor, which in turn prevents their deposition back onto the fabrics being washed

Methodology Applied
Scientific EffectSuspension: Suspension

Implementation Method 3

The clay soil cleaning polymer is selected from the group consisting of ethoxylated oligamines, ethoxylated oligamine methyl quats, ethoxylated oligoamine benzyl quats

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2225355B1Cleaning compositions comprising a multi-polymer system comprising at least one alkoxylated grease cleaning polymer
Publication Date: 2016.05.11 PROCTER & GAMBLE CO
  • EP2225355B1 patent drawing
  • EP2225355B1 patent drawing
  • EP2225355B1 patent drawing

AI summary

Laundry detergents and cleaning compositions which provide improved cleaning benefits that comprise a novel polymer system. The polymer system comprises one or more amphiphilic alkoxylated grease cleaning polymers, and either a clay soil cleaning polymer; or a soil suspending polymer.