Multi-Reaction Zone Reactor for Ammonia Synthesis

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Solution Overview

Problem

Current ammonia production methods, such as the Haber-Bosch process, face inefficiencies due to incomplete reaction conversion and high energy costs, particularly at small scales, and require large-scale economies and fossil fuel-based feedstocks, limiting the use of renewable non-fossil fuels and necessitating the development of more efficient, small-scale reactors with improved catalysts and heat/mass transfer efficiency.

Innovation Solution

A novel catalytic multi-reaction zone reactor system that integrates primary and secondary reaction zones without discrete physical barriers, utilizing Dielectric Barrier Discharge (DBD) nonthermal plasma reactors, controlled temperatures, and specific absorbents like sulphonated micro-porous polymer foams to enhance ammonia production and conversion efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by stationary object

If small-scale reactors are used to produce ammonia, then the reactor footprint and energy efficiency are improved, but the reaction conversion and productivity are reduced

Engineering Contradiction:
Improveenergy efficiencyVSAvoidreaction conversion
Core Design Contradiction:
Use of energy by stationary objectVSProductivity

Solution Approach 1:

The reactor is divided into multiple reaction zones (primary reaction zone for ammonia synthesis, secondary reaction zone for product removal) that work together to achieve high conversion at small scale. The segmentation allows optimized conditions in each zone while maintaining compact overall size.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent implements continuous operation with recirculation of unreacted gases back to the primary reaction zone, ensuring continuous conversion of reactants to products. This continuous action maintains high productivity despite the small scale of individual reaction zones.

Inventive Principle:
Principle #20Continuity of useful action

2Power

If multiple reaction zones are integrated without discrete physical barriers, then heat and mass transfer efficiency are improved, but device complexity increases

Engineering Contradiction:
Improveheat and mass transfer efficiencyVSAvoidreactor structure
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

Multiple reaction zones are merged into a single integrated reactor structure without discrete physical barriers between them. The primary and secondary reaction zones share common walls and fluid pathways, enabling direct heat and mass transfer while simplifying the overall device structure.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Different regions of the integrated reactor are designed with locally optimized properties - the primary reaction zone has catalysts optimized for ammonia synthesis, while the secondary zone has absorbents optimized for product removal. Each zone maintains its specific functional quality within the unified structure.

Inventive Principle:
Principle #3Local quality

3Productivity

If conventional Haber-Bosch process is used at large scale, then productivity is improved, but energy consumption and fossil fuel dependency increase

Engineering Contradiction:
Improveammonia production capacityVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent changes the operating parameters from conventional high-temperature, high-pressure Haber-Bosch conditions to milder conditions enabled by advanced catalysts and plasma activation. This allows productive ammonia synthesis at lower energy consumption levels.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the mechanical intensive compression and heating systems of conventional Haber-Bosch with plasma-based activation and catalytic conversion. This substitution reduces energy consumption while maintaining productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This system increases reaction selectivity and conversion efficiency, enabling the production of ammonia and derivatives with higher yields and energy efficiency, potentially competing with large-scale Haber-Bosch processes while using renewable feedstocks and reducing costs.

Implementation Method 1

The main object of the present invention is to provide, a novel catalytic reactor system in order to increase the overall reaction efficiency in terms of selectivity and conversion

Methodology Applied
Scientific EffectDielectric Barrier Discharge (DBD) plasma: Plasma

Implementation Method 2

producing at least some section of ammonia as a result of balance reaction of ammonia by means of nitrogen and hydrogen catalyst in at least one primary reaction zone

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 3

realizing absorption by means of chemical or physical absorbents of at least some section of ammonia which is in gas form and which is produced in primary reaction zone

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 4

realizing absorption by means of chemical or physical absorbents

Methodology Applied
Scientific EffectChemical absorption: Chemisorption

Implementation Method 5

the temperatures of each reaction zone are controlled by means of at least one heating/cooling coil

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Data Source

PatentUS11498845B2Catalytic multi-reaction zone reactor system
Publication Date: 2022.11.15 AKAY GALIP
  • US11498845B2 patent drawing
  • US11498845B2 patent drawing
  • US11498845B2 patent drawing

AI summary

The present invention is a production method for ammonia and ammonia derivatives in a Multi-Reaction Zone Reactor. Said production method comprising the steps of: a) producing at least some section of ammonia as a result of balance reaction of ammonia by means of nitrogen and hydrogen catalyst in at least one primary reaction zone (RZ-1), b) realizing absorption by means of chemical or physical absorbents of at least some section of ammonia which is in gas form and which is produced in primary reaction zone (RZ-1) in at least one secondary reaction zone (RZ-2) which is not separated by discrete physical barriers with the primary reaction zone (RZ-1).