Multi-Sensor MOS Gas Detection for HVAC Refrigerant Leak Monitoring

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Solution Overview

Problem

Conventional metal oxide semiconductor (MOS) gas sensors used in HVAC/R systems for flammable refrigerant leak detection are prone to false alarms, temporary or permanent poisoning by volatile chemicals, and have limited lifespan, making them unreliable for safety monitoring and requiring complex diagnostic procedures that can interrupt monitoring functions.

Innovation Solution

An air conditioning system with multiple MOS sensors operating at different temperatures, where one sensor is used for primary monitoring and another as a backup or diagnostic sensor, allowing for continuous operation and extended lifespan by comparing resistance measurements across temperature changes, and potentially incorporating a third sensor for additional monitoring and protection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single MOS sensor is used for flammable refrigerant leak detection, then the system is simple and low-cost, but the sensor is prone to false alarms, temporary or permanent poisoning by volatile chemicals, and has limited lifespan

Engineering Contradiction:
Improvesensor reliabilityVSAvoidsensor system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the sensing function into multiple independent MOS sensors (first sensor and second sensor) that operate at different temperatures. Each sensor targets different gas components, segmenting the detection task to reduce false alarms and poisoning effects while maintaining overall system reliability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the operating temperature parameter of the MOS sensors, with the first sensor operating at a first temperature and the second sensor operating at a second temperature. This parameter differentiation allows each sensor to be sensitive to different gas components, improving reliability by reducing cross-sensitivity and poisoning

Inventive Principle:
Principle #35Parameter changes

2Reliability

If diagnostic procedures are implemented to detect sensor poisoning, then sensor reliability can be monitored, but the monitoring function is temporarily interrupted during diagnostics

Engineering Contradiction:
Improvesensor status monitoringVSAvoidmonitoring interruption time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent performs preliminary diagnostic actions by continuously comparing resistance measurements from two sensors operating at different temperatures. This ongoing comparison detects poisoning conditions before they completely disable the monitoring function, allowing for proactive sensor replacement while maintaining continuous safety monitoring

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent assigns different local qualities (operating temperatures) to different sensors, with the first sensor operating at a first temperature and the second sensor at a second temperature. This allows each sensor to have optimized sensitivity characteristics while enabling cross-validation to detect poisoning without interrupting overall monitoring

Inventive Principle:
Principle #3Local quality

3Duration of action of stationary object

If rapid thermal cycling is used to vaporize contaminants and restore sensor function, then sensor lifetime is extended, but the embedded heater experiences thermal cycles that compromise its lifetime

Engineering Contradiction:
Improvesensor operational lifetimeVSAvoidheater durability
Core Design Contradiction:
Duration of action of stationary objectVSStrength

Solution Approach 1:

The patent employs disposable or replaceable MOS sensing elements that can be easily replaced when poisoned or degraded. Instead of attempting to restore expensive or fragile heaters through aggressive thermal cycling, the system accepts that sensors have limited lifespans and focuses on detecting their degradation to prompt timely replacement, thereby protecting the heater from excessive thermal stress

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances the reliability and longevity of gas sensors by reducing false alarms, mitigating poisoning effects, and ensuring continuous monitoring with predictable sensor lifespan, thereby improving safety and operational efficiency in HVAC/R systems.

Implementation Method 1

MOS sensors rely on interaction between gas test components such as hydrogen sulfide or hydrocarbons with adsorbed oxygen on the metal oxide semiconductor surface. In the absence of the gas test components, the metal oxide semiconductor adsorbs atmospheric oxygen at the surface

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

the adsorbed oxygen captures free electrons from the metal oxide semiconductor material, resulting in a measurable level of base resistance of the semiconductor at a relatively high level. Upon exposure to reducing or combustible gas test components such as hydrocarbons or hydrofluorocarbons (HFCs), the gas test component interacts with the adsorbed oxygen, causing it to release tree electrons back to the semiconductor material, resulting in a measurable decrease in resistance

Methodology Applied
Scientific EffectElectron transfer:

Implementation Method 3

an embedded heater would experience thermal cycles all the time

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentEP3622229B1Air conditioning system with multi-sensor gas detection and method of operating the same
Publication Date: 2023.10.25 CARRIER CORP
  • EP3622229B1 patent drawingFigure 1
  • EP3622229B1 patent drawingFigure 2
  • EP3622229B1 patent drawingFigure 3

AI summary

Methods and systems are disclosed in which metal oxide composition electrical resistance is measured in a plurality of sensors to detect flammable or reducing compounds wherein at least one of the plurality of sensors is operated at a temperature or includes a metal oxide composition that is different than a respective temperature or metal oxide composition of another of the plurality of sensors.