Multi-Stage Latex Adhesive Composition for Long-Term Shear

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Solution Overview

Problem

Existing adhesive compositions for pressure-sensitive applications lack sufficient long-term adhesion performance, particularly in terms of shear resistance.

Innovation Solution

An adhesive composition comprising multi-stage latex polymer particles, a linear diamine base, and an ethoxylated surfactant, where the multi-stage latex polymer particles consist of a first-stage polymer containing acrylic acid monomer and a first vinyl monomer, and a second-stage polymer containing methacrylic acid monomer and a second vinyl monomer, with the second vinyl monomer being different, bound together.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional acrylic polymer adhesive compositions are used, then the adhesive provides basic pressure-sensitive adhesion, but the long-term adhesion performance and shear resistance are insufficient

Engineering Contradiction:
Improvelong-term adhesion performanceVSAvoidshear resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies segmentation by using multi-stage latex polymer particles with distinct functional stages: first-stage particles provide adhesion, second-stage particles provide cohesion and shear resistance. This segmentation of functions within the adhesive system resolves the contradiction between long-term adhesion performance and shear resistance by ensuring both properties are addressed by specialized polymer components.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite materials by combining multiple polymer types (acrylic acid-containing, methacrylic acid-containing, vinyl monomer-containing) in specific ratios within the adhesive composition. This composite approach enables the adhesive to simultaneously achieve improved long-term adhesion performance and enhanced shear resistance that cannot be obtained with conventional single-polymer systems.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the adhesive composition is optimized for long-term adhesion performance, then shear resistance improves, but the complexity of the polymer synthesis process increases

Engineering Contradiction:
Improvelong-term adhesion performanceVSAvoidpolymer synthesis process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-synthesizing multi-stage latex polymer particles with specific functional properties before formulating the final adhesive composition. The multi-stage polymerization process creates particles with predetermined adhesion and cohesion characteristics, which simplifies the final adhesive formulation process while achieving the desired long-term performance.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses parameter changes by controlling polymerization conditions (temperature, monomer ratios, stage timing) to produce latex particles with specific glass transition temperatures and functional group compositions. By adjusting these synthesis parameters, the adhesive achieves optimized long-term adhesion performance and shear resistance without requiring overly complex multi-step processes.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS12435203B2Adhesive composition
Publication Date: 2025.10.07 ROHM & HAAS CO
  • US12435203B2 patent drawing
  • US12435203B2 patent drawing
  • US12435203B2 patent drawing

AI summary

The present disclosure provides an adhesive composition. The adhesive composition contains (A) multi-stage latex polymer particles, (B) a linear diamine base, and (C) an ethoxylated surfactant. The (A) multi-stage latex polymer particles include (i) a first-stage polymer containing acrylic acid monomer and a first vinyl monomer, and (ii) a second-stage polymer containing a meth acrylic acid monomer and a second vinyl monomer, with the proviso that the second vinyl monomer is different than the meth acrylic acid monomer. The first-stage polymer is bound to the second-stage polymer.