Multi-Stage Latex Polymers Viscosity Stability

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Solution Overview

Problem

Existing coating compositions with high phosphorus-containing monomers face a trade-off between improved scrub resistance, stain resistance, corrosion resistance, and durability, and viscosity stability, with higher phosphorus content leading to poorer viscosity stability.

Innovation Solution

A multi-stage polymerization process is employed, where the first stage polymer includes a portion of an acrylic monomer and a phosphorus acid monomer, and the second stage polymer includes another portion of both, with specific weight percentages to achieve a targeted glass transition temperature range, resulting in a latex polymer that forms a coating composition with enhanced stability and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phosphorus-containing monomers are increased to improve scrub resistance, stain resistance, corrosion resistance and durability, then coating performance is improved, but coating viscosity stability deteriorates

Engineering Contradiction:
Improvecoating performanceVSAvoidviscosity stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent divides the polymerization process into multiple stages, with phosphorus-containing monomers introduced at specific stages rather than all at once. This segmented approach allows control over phosphorus distribution and concentration, achieving improved coating performance while maintaining viscosity stability by preventing excessive phosphorus content from causing gelation or cross-linking issues.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent optimizes the glass transition temperature (Tg) parameter of the polymer dispersion by selecting specific monomer combinations and ratios. By controlling Tg within a specific range, the patent achieves both improved coating performance from phosphorus-containing monomers and maintained viscosity stability, as Tg control prevents premature gelation and cross-linking that would cause viscosity instability.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If multi-stage polymerization is used to control phosphorus content distribution, then viscosity stability is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveviscosity stabilityVSAvoidprocess complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent implements multi-stage polymerization where phosphorus-containing monomers are added at specific stages rather than all at once. This segmentation allows precise control over phosphorus distribution and concentration, achieving improved viscosity stability while the staged approach actually simplifies process control compared to attempting to manage high phosphorus content in a single stage.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary polymerization stages to build a polymer backbone structure before introducing phosphorus-containing monomers. This preliminary action creates a stable framework that can accommodate phosphorus groups without causing immediate gelation or cross-linking, thereby achieving viscosity stability while maintaining a manageable manufacturing process.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process achieves improved viscosity stability and scrub resistance while maintaining high performance characteristics, as demonstrated by the formulation of coatings with PVC greater than 60%, showing reduced viscosity changes over time and enhanced scrub resistance.

Implementation Method 1

a first monomer mixture having a calculated glass transition temperature of at least about 50 DEG C. is polymerized via free radical emulsion polymerization to obtain a first-stage emulsion polymer

Methodology Applied
Scientific EffectFree radical polymerization: Chemical Bonding

Data Source

PatentEP3157968B1Multi-stage latex polymers, process thereof, and coating compositions made thereof
Publication Date: 2019.08.07 DOW GLOBAL TECHNOLOGIES LLC
  • EP3157968B1 patent drawing

AI summary

Disclosed are a latex polymer of multi-stage polymerization comprising a first stage polymer and a second stage polymer wherein the first stage polymer comprises a first portion of an acrylic monomer and a first portion of a phosphorus acid monomer, and the second stage polymer comprises a second portion of an acrylic monomer and a second portion of a phosphorus acid monomer, a process of making the same, and coating composition made thereof.