Multi-tail Hydrate Inhibitors for Pipeline Blockage Prevention

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Solution Overview

Problem

Gas hydrates form in pipelines during hydrocarbon production, causing blockages that can lead to production losses, equipment damage, and safety hazards, and existing hydrate inhibitors require high concentrations or have limited effectiveness.

Innovation Solution

Development of low-dosage hydrate inhibitors (LDHIs) comprising multiple lipophilic tails, a hydrophilic head, and a linking moiety, which inhibit the formation of gas hydrate agglomerates by preventing nucleation and agglomeration, allowing for effective inhibition at lower concentrations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hydrate inhibitors are used, then hydrate formation is inhibited, but high concentrations are required which increases cost and complexity

Engineering Contradiction:
Improvehydrate inhibition effectivenessVSAvoidinhibitor concentration
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the molecular structure parameters of hydrate inhibitors by introducing multi-tail configurations with specific hydrophobic and hydrophilic components. This structural parameter change enables the inhibitor to achieve enhanced effectiveness at lower concentrations by improving its interaction mechanism with hydrate crystals, thus resolving the contradiction between effectiveness and quantity required

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite molecular structures combining multiple functional components (hydrophobic tails, hydrophilic heads, and linking moieties) into a single inhibitor molecule. This composite structure allows the molecule to simultaneously perform multiple functions: adsorption to hydrate surfaces, disruption of crystal growth, and prevention of agglomeration, thereby achieving high reliability at low concentrations

Inventive Principle:
Principle #40Composite materials

2Reliability

If existing hydrate inhibitors are used, then some protection is provided, but anti-agglomeration properties are insufficient

Engineering Contradiction:
Improveanti-agglomeration effectivenessVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the inhibitor molecule into distinct functional segments: hydrophobic tails for interacting with hydrocarbon phases and hydrate surfaces, hydrophilic heads for water interaction, and linking moieties connecting these components. This segmentation allows each part to perform its specific function optimally, enhancing overall anti-agglomeration effectiveness while maintaining reasonable molecular complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality by赋予ing different regions of the molecule different properties: the hydrophobic tails are designed to interact with non-polar hydrate surfaces, while the hydrophilic heads interact with water molecules. This localized functional differentiation enhances the molecule's ability to prevent agglomeration at specific critical interfaces without requiring complex overall molecular architecture

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The LDHI compounds provide enhanced anti-agglomeration properties, inhibiting hydrate formation more effectively than conventional methods with smaller quantities, thus preventing pipeline blockages and ensuring safer, more reliable hydrocarbon production.

Implementation Method 1

The LDHI compounds provide enhanced anti-agglomeration properties, inhibiting hydrate formation more effectively than conventional methods

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 2

comprising multiple lipophilic tails, a hydrophilic head, and a linking moiety, which inhibit the formation of gas hydrate agglomerates by preventing nucleation and agglomeration

Methodology Applied
Scientific EffectElectrostatic repulsion: Ion Repulsion/Attraction

Data Source

PatentUS10364385B2Multi-tail hydrate inhibitors
Publication Date: 2019.07.30 HALLIBURTON ENERGY SERVICES INC
  • US10364385B2 patent drawing
  • US10364385B2 patent drawing
  • US10364385B2 patent drawing

AI summary

Low-dosage hydrate inhibitor (“LDHI”) compounds comprising multiple lipophilic tails and a hydrophilic head may be employed into fluids to inhibit agglomeration of hydrates, among other things. Suitable hydrophilic heads may include quaternary or tertiary ammonium cation moieties, and combinations thereof. Such LDHI compounds in some embodiments may include reaction products of DETA and/or other amines, fatty acid(s), and, optionally, alkyl halide(s). Compounds according to some embodiments may be employed in fluids in various environments, such as a conduit penetrating a subterranean formation, or a conduit carrying fluid in an industrial setting.