Self-Aligned Multi-Tier Nanostructure Fabrication via Spacer Etching

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Solution Overview

Problem

Current nanoimprint lithography techniques require multiple steps and intermediate alignment/overlay processes to create multi-tier nanostructures, which becomes increasingly challenging as critical dimensions scale down, hindering the patterning of high-density multi-level nanoelectronic circuits.

Innovation Solution

A method for fabricating bilaterally symmetric multi-tier structures using a single lithography step by patterning a pair of grating structures on a substrate, transferring the pattern, depositing spacer material, and etching to define side wall spacers, allowing for the formation of self-aligned multi-tier structures without the need for alignment or overlay steps.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If multiple lithography steps are used to create multi-tier nanostructures, then the structure complexity increases, but the manufacturing precision deteriorates due to alignment and overlay challenges

Engineering Contradiction:
Improvemulti-tier structure complexityVSAvoidalignment precision
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent implements self-aligned multi-tier nanostructure fabrication where the first and second grating structures automatically define each other's positions through their mutual geometric relationships. The side wall spacers formed from the first grating structures serve as self-generated alignment references for the second grating structures, eliminating the need for external alignment procedures and maintaining sub-50 nm precision without multiple lithography steps.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The fabrication process is segmented into distinct functional stages: forming sacrificial first grating structures, depositing spacer material, removing the first gratings, and forming second grating structures using the spacers as templates. This segmentation allows each stage to be optimized independently while maintaining overall precision, resolving the contradiction between structure complexity and manufacturing precision.

Inventive Principle:
Principle #1Segmentation

2Device complexity

If multiple lithography steps with alignment are used, then multi-tier structures can be formed, but the process time increases

Engineering Contradiction:
Improvemulti-tier structure complexityVSAvoidfabrication time
Core Design Contradiction:
Device complexityVSLoss of time

Solution Approach 1:

The patent merges the patterning of multiple tiers into a single lithography step by using self-aligned side wall spacer formation. The first and second grating structures are created simultaneously through one exposure and development cycle, with their relative positions determined by the spacer thickness rather than by sequential alignment operations, thereby dramatically reducing fabrication time while maintaining multi-tier complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The side wall spacers are formed as preliminary structures before the second grating pattern is defined. These spacers pre-establish the geometric relationships and spacing between tiers, allowing the second grating to be formed directly without time-consuming alignment measurements or iterative adjustments, thus accelerating the overall fabrication process.

Inventive Principle:
Principle #10Preliminary action

3Quantity of substance

If critical dimensions are scaled down, then the device density increases, but the alignment difficulty increases

Engineering Contradiction:
Improvedevice densityVSAvoidalignment difficulty
Core Design Contradiction:
Quantity of substanceVSDifficulty of detecting and measuring

Solution Approach 1:

The patent replaces mechanical alignment systems (alignment marks, overlay tools, and physical registration procedures) with a geometric field-based approach where electromagnetic fields define the grating patterns, and the patterns themselves define subsequent patterns through self-alignment. This substitution enables sub-50 nm critical dimensions to be maintained with high device density while eliminating the measurement and alignment difficulties that plague scaled-down multi-step processes.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the creation of high-resolution, sub-50 nm multi-tier nanoimprint templates and devices like silicon tube capacitors and wire grid polarizers with improved performance, eliminating the complexity and challenges associated with traditional multi-step alignment processes.

Implementation Method 1

transferred the patterned pair of grating structures into the substrate material using a resist mask

Methodology Applied
Scientific EffectEtching:

Implementation Method 2

depositing spacer material until an empty space within each of the pair of grating structures is filled

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

etching the spacer material anisotropically to define side wall spacers on the outer edges of the pair of grating structures

Methodology Applied
Scientific EffectAnisotropic etching:

Implementation Method 4

etching the substrate material using the side wall spacers as an etch mask to form a second lower level

Methodology Applied
Scientific EffectEtching with mask:

Data Source

PatentUS9972699B1Fabricating large area multi-tier nanostructures
Publication Date: 2018.05.15 BOARD OF RGT THE UNIV OF TEXAS SYST
  • US9972699B1 patent drawing
  • US9972699B1 patent drawing
  • US9972699B1 patent drawing

AI summary

Methods for fabricating and replicating self-aligned multi-tier nanoscale structures for a variety of cross-sectional geometries. These methods can utilize a single lithography step whereby the need for alignment and overlay in the process is completely eliminated thereby enabling near-zero overlay error. Furthermore, techniques are developed to use these methods to fabricate self-aligned nanoscale multi-level/multi-height patterns with various shapes for master templates, replica templates and nanoimprint based pattern replication. Furthermore, the templates can be used to pattern multiple levels in a sacrificial polymer resist and achieve pattern transfer of the levels into a variety of substrates to form completed large area nanoelectronic and nanophotonic devices using only one patterning step.