Multi-Zone Reactor for High-Octane Gasoline Production

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Solution Overview

Problem

Existing methods for producing high-octane gasolines face limitations in reactor design, leading to restricted production capacity, temperature control issues, and fractional composition restrictions, resulting in suboptimal gasoline quality with high benzene and high-melting-point component content.

Innovation Solution

A reactor design with at least two reaction zones and separate supply of methanol and/or oxygenates to each zone, allowing for improved mixing and temperature control, reduces benzene content and high-melting-point components, and increases reactor volume, enhancing gasoline quality and production capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a single reaction zone is used in the reactor, then the reactor design is simple, but the production capacity is restricted and temperature control is difficult

Engineering Contradiction:
Improveproduction capacityVSAvoidreactor design complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The reactor is divided into multiple reaction zones (at least two) with different functional characteristics. The first reaction zone is designed for initial conversion with specific temperature conditions, while the second reaction zone performs further conversion with different temperature control, allowing independent optimization of each zone for maximum production capacity

Inventive Principle:
Principle #1Segmentation

2Ease of operation

If methanol and oxygenates are supplied together in a single stream, then the supply system is simple, but mixing efficiency and temperature control are suboptimal

Engineering Contradiction:
Improvemixing efficiencyVSAvoidsupply system complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The feedstock supply system is segmented into separate streams: one for hydrocarbon fractions and another for methanol/oxygenates. These separate streams are introduced at different points into the reaction zones, allowing precise control of mixing timing and location, which improves conversion efficiency and temperature management

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Methanol and oxygenates are pre-heated separately before being introduced into the reaction zones. This preliminary heating action ensures optimal temperature conditions upon mixing and reaction, improving overall process efficiency without requiring complex in-situ heating systems

Inventive Principle:
Principle #10Preliminary action

3Productivity

If the reactor volume is increased to improve production capacity, then more gasoline can be produced, but the temperature control becomes more difficult and design complexity increases

Engineering Contradiction:
Improveproduction capacityVSAvoidtemperature control
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

By dividing the reactor into multiple zones, each zone can be independently sized and temperature-controlled. This allows the total reactor volume to be increased for higher production capacity while maintaining manageable temperature control in each individual zone through separate heating/cooling systems

Inventive Principle:
Principle #1Segmentation

4Manufacturing precision

If conventional single-zone reaction is used, then the process is simple, but the gasoline quality is suboptimal with high benzene and high-melting-point components

Engineering Contradiction:
Improvegasoline qualityVSAvoidreactor configuration
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The multi-zone reactor configuration enables staged conversion processes where the first zone performs initial cracking and reforming, and the second zone completes the conversion and removes unwanted components. This segmented approach achieves superior gasoline quality with controlled benzene and high-melting-point component content

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different reaction conditions are created in different zones: the first zone operates with conditions optimized for initial conversion, while the second zone provides conditions optimized for quality enhancement and impurity removal. Each zone has tailored temperature, pressure, and catalyst characteristics to achieve local optimization of product quality

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution increases the Research Octane Number (RON) of produced gasolines, reduces undesirable compounds, and allows for larger reactor volumes, improving the antiknock rating and quality of the gasoline while simplifying reactor design.

Implementation Method 1

the reaction is carried out in the presence of a zeolite-containing catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

feedstock is heated and supplied into a reactor

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS20230235236A1Method for producing high-octane motor gasolines of low-octane hydrocarbon fractions, fractions of gaseous olefins and oxygenates and a plant for the method embodiment
Publication Date: 2023.07.27 UNIVERSAL FUEL TECHNOLOGIES INC
  • US20230235236A1 patent drawing
  • US20230235236A1 patent drawing

AI summary

The invention relates to method and plant for the production of high-octane gasolines from raw hydrocarbon fractions, fractions of gaseous olefins and oxygenates. A method has been proposed, wherein the feedstock component flow is supplied to a unit for supplying flows to be treated, into the reactor, wherein the reaction is carried out in the presence of a zeolite-containing catalyst, high-octane gasoline is isolated by separation of the conversion product, while diverting simultaneously the reaction water and the exhaust gases. A reactor contains at least two reaction zones, between which there are further arranged means for mixing the reaction product from the previous reaction zone and the supplied oxygenates and olefin-containing feed-stock, whereas using the unit for supplying flows there is supplied a flow oxygenates and olefin-containing feedstock and the flow of raw hydrocarbon fractions into the first reaction zone of the reactor, and the flow oxygenates and olefin-containing feedstock into the second reaction zone of the reactor.