Multi-Zone Reactor for High-Octane Gasoline Production

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Solution Overview

Problem

Existing methods for producing high-octane gasolines face limitations in reactor design, leading to restricted production capacity, temperature control issues, and fractional composition restrictions, resulting in suboptimal gasoline quality with high benzene and durene content.

Innovation Solution

A reactor design with multiple reaction zones and separate supply of methanol and olefin-containing feedstocks to each zone allows for improved temperature control and increased reactor volume, reducing benzene and durene content through targeted mixing and heating strategies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a single reaction zone reactor is used, then the reactor design is simple, but the production capacity is restricted and temperature control is difficult

Engineering Contradiction:
Improveproduction capacityVSAvoidreactor design complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The reactor is divided into multiple reaction zones (first reaction zone, second reaction zone, etc.) with separate feedstock supply systems for each zone. This segmentation allows independent control of reaction conditions in each zone, enabling better temperature control and increased production capacity without requiring a single complex reactor design.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If feedstock is supplied to a single reaction zone, then the operation is simple, but the gasoline quality is suboptimal with high benzene and durene content

Engineering Contradiction:
Improvegasoline qualityVSAvoidfeedstock supply operation
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

Different feedstock components (methanol, olefin-containing feedstock, raw hydrocarbon fractions) are supplied to different reaction zones based on their specific requirements. The first reaction zone receives methanol and raw hydrocarbon fractions, while the second reaction zone receives olefin-containing feedstock and conversion products from the first zone. This local quality approach optimizes the chemical environment in each zone to reduce benzene and durene content in the final gasoline product.

Inventive Principle:
Principle #3Local quality

3Temperature

If reaction zones are combined into one, then the reactor volume is smaller, but the temperature control throughout the catalyst bed is poor

Engineering Contradiction:
Improvetemperature controlVSAvoidreactor volume
Core Design Contradiction:
TemperatureVSVolume of stationary object

Solution Approach 1:

The reactor is segmented into multiple reaction zones with independent feedstock supply and mixing capabilities. Each zone can be optimized for specific temperature ranges and reaction conditions, allowing precise temperature control throughout the catalyst bed while maintaining a reasonable total reactor volume through efficient spatial arrangement.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the octane rating of produced gasolines, reduces undesirable compounds, and increases production capacity while maintaining a simpler reactor design, achieving higher quality gasoline with reduced benzene and durene levels.

Implementation Method 1

the reaction is carried out in the presence of a zeolite-containing catalyst

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

the feedstock is heated and supplied into a reactor

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS11427770B2Method for producing high-octane motor gasolines of low-octane hydrocarbon fractions, fractions of gaseous olefins and oxygenates and a plant for the method embodiment
Publication Date: 2022.08.30 UNIVERSAL FUEL TECHNOLOGIES INC
  • US11427770B2 patent drawing
  • US11427770B2 patent drawing

AI summary

The invention relates to method and plant for the production of high-octane gasolines from raw hydrocarbon fractions, fractions of gaseous olefins and oxygenates. A method has been proposed, wherein the feedstock component flow is supplied to a unit for supplying flows to be treated, into the reactor, wherein the reaction is carried out in the presence of a zeolite-containing catalyst, high-octane gasoline is isolated by separation of the conversion product, while diverting simultaneously the reaction water and the exhaust gases. A reactor contains at least two reaction zones, between which there are further arranged means for mixing the reaction product from the previous reaction zone and the supplied oxygenates and olefin-containing feedstock, whereas using the unit for supplying flows there is supplied a flow oxygenates and olefin-containing feedstock and the flow of raw hydrocarbon fractions into the first reaction zone of the reactor, and the flow oxygenates and olefin-containing feedstock into the second reaction zone of the reactor.