Multicolor Light-Emitting Layer Stack With Exciplex-Phosphorescence
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
Existing multicolor light-emitting elements using fluorescence and phosphorescence require a large number of layers, which hinders practical application and results in inefficient emission due to quenching and nonradiative deactivation processes, particularly when using host materials with high triplet excited energy levels.
Innovation Solution
A light-emitting element with a stacked-layer structure comprising a first light-emitting layer exhibiting exciplex fluorescence and a second light-emitting layer exhibiting phosphorescence, where the exciplex is formed from two organic compounds with closely aligned singlet and triplet excited levels, allowing for efficient energy transfer and reduced layer complexity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Adaptability or versatility
If a large number of layers are used in multicolor light-emitting elements to achieve different emission colors, then color diversity is improved, but device complexity and manufacturing difficulty increase significantly
Solution Approach 1:
The patent combines multiple light-emitting layers into a stacked-layer structure where a first light-emitting layer (fluorescence) and a second light-emitting layer (phosphorescence) are vertically arranged. This merging approach achieves multicolor emission (yellow from fluorescence + red from phosphorescence = orange-red overall emission) without requiring separate independent layers for each color, thereby reducing overall device complexity while maintaining color diversity.
Solution Approach 2:
The stacked light-emitting layer structure serves multiple functions simultaneously: it generates different emission colors through fluorescence and phosphorescence mechanisms, controls energy transfer between layers, and manages triplet excited state distribution. This multi-functionality allows a single stacked structure to replace what would traditionally require multiple separate functional layers, reducing device complexity.
2Illumination intensity
If host materials with high triplet excited energy levels are used, then phosphorescence emission is improved, but energy transfer losses and quenching increase due to nonradiative deactivation processes
Solution Approach 1:
The patent carefully selects and adjusts the triplet excited energy levels of host materials in both the first and second light-emitting layers. By optimizing these energy level parameters, the patent ensures efficient energy transfer from the fluorescence layer to the phosphorescence layer while minimizing nonradiative deactivation and quenching losses. This parameter optimization allows high phosphorescence emission efficiency without excessive energy loss.
Solution Approach 2:
The first light-emitting layer (fluorescence) acts as an intermediary energy transfer mediator to the second light-emitting layer (phosphorescence). This intermediary structure enables controlled energy transfer from the fluorescence emission to excite the phosphorescence material, reducing direct energy loss and quenching that would occur with improper host material selection. The intermediary layer facilitates efficient energy cascading while minimizing nonradiative losses.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This structure enables high emission efficiency with reduced layer count, facilitating cost-effective manufacturing and extended lifetime by minimizing energy transfer losses and quenching, suitable for multicolor and white light emission.
Implementation Method 1
a first light-emitting layer exhibiting light emission from a first exciplex
Implementation Method 2
a second light-emitting layer exhibiting phosphorescence
Implementation Method 3
since intersystem crossing (i.e., transfer from a singlet excited state to a triplet excited state) easily occurs in a phosphorescent compound
Data Source
AI summary
A multicolor light-emitting element using fluorescence and phosphorescence, which has a small number of manufacturing steps owing to a relatively small number of layers to be formed and is advantageous for practical application can be provided. In addition, a multicolor light-emitting element using fluorescence and phosphorescence, which has favorable emission efficiency is provided. A light-emitting element which includes a light-emitting layer having a stacked-layer structure of a first light-emitting layer exhibiting light emission from a first exciplex and a second light-emitting layer exhibiting phosphorescence is provided.


