Multi-Core Optical Fiber Photoreactor for In-Situ Reaction Sensing

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Solution Overview

Problem

Existing photoreactors face challenges in efficiently monitoring physical conditions like temperature and reactant flow without compromising the available reaction volume or photocatalytic process efficiency, as conventional monitoring equipment can impede the reaction.

Innovation Solution

A multi-core optical fiber is used, with one core for supplying optical radiation and another core for sensing physical conditions, allowing for integrated monitoring without affecting the reaction volume or efficiency, utilizing features like Raman scattering and fiber gratings for precise temperature and flow measurements.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional monitoring equipment is introduced into the photoreactor to monitor physical conditions, then measurement precision is improved, but the available reaction volume is reduced and the photocatalytic process efficiency is impaired

Engineering Contradiction:
Improvephysical conditions monitoringVSAvoidavailable reaction volume
Core Design Contradiction:
Measurement precisionVSVolume of moving object

Solution Approach 1:

The patent replaces conventional mechanical monitoring equipment with an optical sensing system. The optical sensor uses light transmission through the reaction medium to measure physical conditions (temperature, viscosity, concentration) without physical contact or mechanical components in the reaction volume, thereby maintaining full reaction volume while achieving precise measurements.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces an optical intermediary (light) as the sensing medium. Instead of placing physical sensors in the reaction mixture, light is used as an intermediary carrier to probe the physical conditions of the reaction medium. The optical sensor detects changes in light properties (absorption, scattering, refractive index) that correlate with physical conditions, enabling indirect measurement without contamination or volume displacement.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Measurement precision

If conventional monitoring equipment is introduced into the photoreactor to monitor physical conditions, then measurement precision is improved, but the photocatalytic process efficiency is impaired

Engineering Contradiction:
Improvephysical conditions monitoringVSAvoidphotocatalytic process efficiency
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent replaces mechanical monitoring equipment with an optical sensing system that uses light transmission to measure physical conditions. This substitution eliminates mechanical interference with the photocatalytic process while maintaining measurement precision, thereby preserving productivity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses light as an intermediary to probe physical conditions without directly interfering with the photocatalytic reaction. The optical sensor detects physical conditions through light-matter interactions that do not disrupt the chemical reaction, enabling continuous monitoring while maintaining high process efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If a separate light source is added for the sensing core, then measurement precision is improved for longer optical fibers, but device complexity increases

Engineering Contradiction:
Improvetemperature sensing accuracyVSAvoidoptical fiber system structure
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent segments the optical fiber into two distinct functional cores: a first core optimized for delivering high optical power to the reaction medium, and a second core optimized for sensing physical conditions. This segmentation allows each core to be independently optimized for its specific function while sharing the same fiber infrastructure, reducing overall system complexity compared to using separate fiber cables.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent merges the power delivery and sensing functions into a single multi-core optical fiber bundle. By combining both functions in one integrated fiber structure, the system reduces the number of separate components (power source, sensing source, multiple fibers) while maintaining the ability to independently optimize each function, thereby reducing device complexity.

Inventive Principle:
Principle #5Merging (Combining)

Data Source

PatentEP4656284A1Photoreactor and method of operating the same
Publication Date: 2025.12.03 NEDERLANDSE ORG VOOR TOEGEPAST NATUURWETENSCHAPPELIJK ONDERZOEK TNO
  • EP4656284A1 patent drawingFigure 1
  • EP4656284A1 patent drawingFigure 1A
  • EP4656284A1 patent drawingFigure 1B

AI summary

A photoreactor (1) is disclosed herein that comprises a reactor space (10), an optical power source (20), an optical sensing device (30) and a multi-core optical fiber (40) extending into the reactor space. The multi-core optical fiber has a first core (41) that is optically coupled to the optical power source and the multi-core optical fiber is configured to laterally outcouple optical radiation from the first core into the reactor space. The multi-core optical fiber has a second core (42) that is optically coupled to the optical sensing device. A cross-sectional surface of the first core is at least as large as a cross-sectional surface of the second core.