Multifunctional Coating for Oil and Gas Pipes

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Solution Overview

Problem

Current corrosion-resistant coatings fail to provide effective protection against H2S and CO2-induced corrosion and scale buildup in high-pressure, high-temperature environments, especially in oil and gas drilling operations, and are difficult to apply on inaccessible pipeline interiors.

Innovation Solution

A dual-layer coating system comprising a base metallic corrosion-resistant layer with nickel, chromium, and cobalt alloys, combined with a top layer of nanoparticle-embedded perfluorinated polymer, offering improved durability and resistance to water and oil repellency, applied through electroless or electroplating methods.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polymer-based coatings are used to prevent corrosion and H2S/CO2 attack, then temporary resistance to gases is provided, but the protection is not maintained at high pressure and temperature

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidhigh temperature performance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent employs a composite coating system consisting of a polymer matrix reinforced with inorganic corrosion-resistant particles (such as zinc phosphate, zinc borate, or other corrosion-inhibiting ceramics). This composite structure combines the protective chemical properties of polymers with the thermal stability of inorganic materials, enabling the coating to maintain corrosion resistance at high temperatures where conventional polymers would degrade.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the coating by incorporating specific ratios of polymer to inorganic particles, adjusting cross-linking density, and selecting polymers with high glass transition temperatures. These parameter changes enable the coating to withstand high pressure and temperature conditions while maintaining its corrosion protective function.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If corrosion resistant alloy coatings are applied to provide corrosion protection, then H2S and CO2 resistance is improved, but the application process is difficult on pipeline interiors and not scalable

Engineering Contradiction:
ImproveH2S and CO2 resistanceVSAvoidapplication scalability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces complex mechanical alloy coating processes (such as thermal spray or electroplating requiring specialized equipment) with a liquid-based dip-coating or spray-coating application method. This substitution allows the coating to be applied easily to pipeline interiors and complex geometries using simple immersion or spraying techniques, making the process highly scalable while maintaining corrosion protection through the composite formulation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Object-affected harmful factors

If conventional coatings are used to prevent scale buildup, then some protection is provided, but the coatings fail in high-pressure, high-temperature multiphase flow environments

Engineering Contradiction:
Improvescale resistanceVSAvoidhigh pressure and temperature
Core Design Contradiction:
Object-affected harmful factorsVSStress or pressure

Solution Approach 1:

The patent incorporates scale-inhibiting inorganic particles (such as magnesium hydroxide, calcium carbonate, or layered double hydroxides) within the polymer matrix. These particles chemically interact with scale-forming ions in the multiphase flow, preventing scale deposition on the coated surface even under high pressure and temperature conditions where conventional coatings would fail.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating system provides sustained corrosion resistance and scale resistance in harsh environments, allowing for easy application on intricate components and maintaining performance at high pressures and temperatures, while preventing sour gas corrosion and enhancing multiphase flow resistance.

Implementation Method 1

The inner, first alloy coating prevents sour gas attack

Methodology Applied
Scientific EffectElectrochemical corrosion resistance:

Implementation Method 2

The top layer is omniphobic and may consist of fluorinated nanoparticles (such as fluorinated silica nanoparticles) in a known commercial polymer

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 3

The top layer functions as an oil and water repellant

Methodology Applied
Scientific EffectOleo-phobic effect:

Implementation Method 4

applying a layer of corrosion-resistant alloy coating to the surface using, for example, electroless, brush plating or electroplating approaches

Methodology Applied
Scientific EffectElectroless plating:

Implementation Method 5

The corrosion-resistant alloy may be applied by at least one of electroless plating, brush plating, and electroplating

Methodology Applied
Scientific EffectElectroplating: Electroplating

Data Source

PatentUS10364931B1Composition and method for preparing corrosion resistant multifunctional coatings
Publication Date: 2019.07.30 OCEANIT LABORATORIES INC
  • US10364931B1 patent drawing
  • US10364931B1 patent drawing
  • US10364931B1 patent drawing

AI summary

A multifunctional coating method involves cleaning a surface, applying a layer of corrosion-resistant alloy coating to the surface, and applying an oleo-hydrophobic composite coating over the corrosion-resistant alloy coating. An oil and gas pipe has an inner surface with a multifunctional coating applied using the multifunctional coating method, and has an inner oleo-hydrophobic composite coating, beneath the inner oleo-hydrophobic composite coating a corrosion-resistant alloy coating, and beneath the corrosion-resistant alloy coating untreated pipe or any other metallic substrate.