Multilayer Battery Separator Thermal Shutdown Mechanism
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Solution Overview
Problem
Lithium-ion batteries face safety concerns due to increased heat generation with higher energy density, leading to potential explosions, as conventional battery separators lack effective thermal stability and ion transportation control.
Innovation Solution
A multilayer battery separator comprising a porous polyethylene film coated with a thermal resistant film, such as polyvinylidene fluoride (PVDF) and cellulose or polyethylene glycol, providing adjustable permeability and thermal shutdown properties to manage heat and ion transport safely.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Power
If energy density of the battery is increased to improve performance, then power and size of the battery increase, but heat generation increases leading to potential explosion
Solution Approach 1:
The patent utilizes the phase transition property of polyethylene material in the separator. When temperature reaches the melting point of polyethylene (approximately 165°C), the separator undergoes phase transition from solid to molten state, automatically closing the pores and shutting down ion transport. This thermal shutdown mechanism prevents heat accumulation and potential explosion without requiring additional active cooling systems.
Solution Approach 2:
The battery separator acts as an intermediary component between the positive and negative electrodes. It mediates the thermal management by absorbing and dissipating heat through its thermal conduction properties while simultaneously providing a physical barrier that prevents direct contact between electrodes. The separator's porous structure also allows controlled ion transport, balancing electrical function with thermal safety.
2Reliability
If a battery separator is used to prevent physical contact between electrodes to improve safety, then battery safety is improved, but ion transport control is insufficient leading to overheating
Solution Approach 1:
The patent employs a porous polyethylene separator with specifically controlled pore structure. The porous design allows efficient ion transport through the separator under normal operating conditions, maintaining high productivity. When thermal runaway occurs, the pores automatically close due to melting, providing passive thermal shutdown protection. This dual-function porous structure simultaneously achieves both ion transport efficiency and thermal safety without requiring active control systems.
Solution Approach 2:
The patent optimizes key parameters of the separator including pore size distribution, porosity (typically 30-80%), and thickness (typically 15-50 μm). By adjusting these parameters, the separator can be tuned to provide optimal ion transport efficiency at operating temperatures while ensuring adequate thermal shutdown capability. The polyethylene crystallinity and molecular weight are also controlled to achieve the desired melting point and mechanical properties.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composite film enhances battery safety by controlling ion transport and thermal stability, preventing overheating and maintaining function even after the polyethylene film melts, thus reducing the risk of explosion and ensuring efficient charging/discharging.
Implementation Method 1
the porous polyethylene film melts down and breaks
Implementation Method 2
a porous thermal resistant film having an appropriate pore size, so that ions inside the battery can have a better transportation rate
Data Source
AI summary
A multilayer battery separator is provided. The multilayer battery separator includes a porous polyethylene (PE) film, and a porous thermal resistant film selected from a group consisting of: a weight ratio of polyvinylidene fluoride (PVDF) and cellulose of 90/10-40/60; a weight ratio of polyvinylidene fluoride and polyethylene glycol (PEG) of 99/1-85/15; and polyimide (PI), and combinations thereof. A method for manufacturing the multilayer battery separator is also provided.