Multi-Layer Bond Coat for Turbine Oxidation and Spallation Resistance

Solution Overview

Problem

Turbine engine components face challenges in withstanding increasingly harsh operating conditions due to rising maximum use temperatures, as existing thermal barrier coating systems lack sufficient oxidation and spallation resistance, leading to reduced component lifespan and efficiency.

Innovation Solution

A multi-layer metallic bond coat system is applied to turbine engine components, comprising an oxidation resistant layer and a spallation resistant layer, deposited using cathodic arc deposition techniques, followed by diffusion heat treatment to enhance adhesion and mechanical densification, and finally topped with a thermal barrier coating.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single-layer bond coat is used, then the coating system is simpler and easier to manufacture, but the oxidation and spallation resistance is insufficient

Engineering Contradiction:
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The bond coat is divided into two distinct layers: an oxidation-resistant layer (containing Al, Cr, Hf) and a spallation-resistant layer (containing Ta, W, Mo). This segmentation allows each layer to specialize in providing its specific protective function, with the oxidation-resistant layer preventing chemical degradation and the spallation-resistant layer preventing delamination, thereby resolving the contradiction between simplicity and reliability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite multi-layer structure combining different metallic alloys with complementary properties. The oxidation-resistant layer uses Al-Cr-Hf based materials while the spallation-resistant layer uses Ta-W-Mo based materials. This composite approach leverages the synergistic effects of different materials to achieve both oxidation and spallation resistance simultaneously.

Inventive Principle:
Principle #40Composite materials

2Productivity

If maximum use temperature is increased for efficiency, then energy efficiency improves, but the harsh operating conditions reduce component lifespan

Engineering Contradiction:
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters of the bond coat by introducing specific elements (Hf, Ta, W, Mo) in controlled concentrations. These compositional changes enable the coating to withstand higher temperatures and more harsh operating conditions, allowing the turbine components to operate at elevated temperatures for improved efficiency while maintaining extended lifespan through enhanced thermal and oxidation stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layer bond coat system demonstrates significant improvements in spallation and oxidation resistance, extending component life and enhancing thermal efficiency by 200% to 800% and 15% to 44% respectively compared to conventional coatings, thereby improving part life and reducing fuel consumption.

Implementation Method 1

deposited using cathodic arc deposition techniques

Methodology Applied
Scientific EffectCathodic arc deposition: Cathodic Arc Deposition

Implementation Method 2

followed by diffusion heat treatment to enhance adhesion

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS8497028B1Multi-layer metallic coating for TBC systems
Publication Date: 2013.07.30
  • US8497028B1 patent drawing
  • US8497028B1 patent drawing
  • US8497028B1 patent drawing

AI summary

A coating system for a turbine engine component having a substrate includes a multi-layer bond coat applied to the substrate. The multi-layer bond coat has an oxidation resistant layer and a spallation resistant layer deposited over the oxidation resistant layer. Processes for forming the coating system are described.