Multilayer Carbon Nanotube Foam Structures

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Solution Overview

Problem

Existing methods for synthesizing carbon nanotube (CNT) foams exhibit enormous variability in material properties, limiting their practical application due to inconsistent energy dissipation and mechanical performance under compression.

Innovation Solution

A method involving the synthesis of nominally-aligned carbon nanotubes sandwiched between polymeric or metal layers, creating multilayer structures that enhance mechanical properties and energy absorption through compliant polymer interlayers and buckypaper integration, which provide adhesion and reinforcement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If standard thermal chemical vapor deposition techniques are used to synthesize CNT foams, then the material can be readily synthesized with low density and energy dissipation capabilities, but the material properties exhibit enormous variability limiting practical application

Engineering Contradiction:
Improvereadily synthesizedVSAvoidmaterial properties variability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite structure by sandwiching CNT layers between polymeric layers, forming a multilayer composite material. This composite approach combines the energy dissipation capabilities of CNTs with the structural stability and adhesion properties of polymers, resulting in more consistent and reliable material properties while maintaining ease of manufacture through sequential layering processes

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent segments the CNT foam structure into multiple discrete layers, each sandwiched between polymeric layers. This segmentation allows for better control over the mechanical properties and energy absorption characteristics of each layer, reducing overall variability while maintaining the low-density foam structure and ease of fabrication

Inventive Principle:
Principle #1Segmentation

2Strength

If multilayer structures with polymeric interlayers are used, then adhesion and reinforcement are provided improving mechanical properties, but the structure complexity increases

Engineering Contradiction:
Improvemechanical propertiesVSAvoidstructure complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The polymeric layers serve as intermediary elements between CNT layers, providing adhesion and reinforcement. These intermediary layers bond the CNT layers together, improving the overall mechanical strength and structural integrity of the composite material, while the simple sandwich structure minimizes the actual increase in fabrication complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

By creating a composite material system with alternating CNT and polymeric layers, the patent achieves enhanced mechanical properties through the synergistic combination of materials. The polymeric layers provide structural support and adhesion, while the CNT layers contribute energy dissipation capabilities, resulting in a composite with superior overall performance despite the multilayer structure

Inventive Principle:
Principle #40Composite materials

3Strength

If CNTs are sandwiched between metal layers or metal foils, then mechanical reinforcement is provided, but the weight of the structure increases

Engineering Contradiction:
Improvemechanical reinforcementVSAvoidstructure weight
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The patent explores changing the material parameter of the interlayer from polymeric to metal, which alters the weight-to-strength ratio. While metal layers provide superior mechanical reinforcement, they increase the overall structure weight. This parameter change allows optimization based on specific application requirements where either lightweight (polymer) or high-strength (metal) characteristics are prioritized

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer structures demonstrate improved energy absorption capabilities, up to three orders of magnitude better than conventional foams, with enhanced mechanical damping and localized deformation, comparable to biological materials like cartilage, and superior force mitigation in dynamic conditions.

Implementation Method 1

nominally-aligned arrays of carbon nanotubes (CNTs) are known to behave as low-density energy dissipative foams under compression

Methodology Applied
Scientific EffectEnergy dissipation: Damping

Implementation Method 2

The material can be readily synthesized using standard thermal chemical vapor deposition techniques

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS9616635B2Multilayer foam structures of nominally-aligned carbon nanotubes (CNTS)
Publication Date: 2017.04.11 CALIFORNIA INST OF TECH
  • US9616635B2 patent drawing
  • US9616635B2 patent drawing
  • US9616635B2 patent drawing

AI summary

A method for making a multilayer foam structure of nominally-aligned carbon nanotubes (CNTs) is disclosed. The method comprises synthesizing a layer of CNTs and sandwiching the layer of CNTs between two polymeric layers, or between two metallic layers or foils.