Multilayer Container Two-Color Molding Viscosity Control

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Solution Overview

Problem

The challenge is to produce a multilayer container using two-color molding that maintains transparency, as existing methods often result in poor transparency due to interface unevenness between the polyester resin outer layer and the polyamide resin inner layer.

Innovation Solution

The solution involves adjusting the relative viscosity of the polyamide resin in the inner layer to a range of 1.8 to 2.8, using a xylylenediamine-based polyamide resin with specific structural units, and controlling the thickness ratio between the outer and inner layers to achieve optimal transparency and barrier properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If two-color molding is used to produce a multilayer container with polyester resin outer layer and polyamide resin inner layer, then the container can achieve good barrier properties, but the transparency is deteriorated due to interface unevenness

Engineering Contradiction:
Improvebarrier propertiesVSAvoidtransparency
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent applies parameter changes by controlling the relative viscosity of the polyamide resin within a specific range (1.8 to 2.8) to resolve the contradiction between barrier properties and transparency. This viscosity control ensures proper flow and bonding at the interface between layers, achieving both good barrier performance and high transparency without the interface unevenness that plagues conventional two-color molding processes.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the polyamide resin relative viscosity is increased to improve barrier properties, then the oxygen and butyl acetate barrier properties are enhanced, but the interface unevenness increases and transparency deteriorates

Engineering Contradiction:
Improvebarrier propertiesVSAvoidinterface unevenness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent precisely controls the relative viscosity parameter of the polyamide resin within the range of 1.8 to 2.8, which is the optimal range that simultaneously achieves excellent barrier properties (oxygen transmission rate of 8.0×10^-3 cc/pkg·day or less and butyl acetate barrier properties of 0.015 g/bottle·day or less) while maintaining smooth interfaces and high transparency. This parameter optimization resolves the contradiction between barrier performance and manufacturing precision.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If a conventional polyamide resin is used in two-color molding, then the production process is simple, but the transparency and interface quality are poor

Engineering Contradiction:
Improveproduction process simplicityVSAvoidtransparency
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent maintains the simplicity of the two-color molding process while dramatically improving transparency by optimizing the relative viscosity parameter of the polyamide resin to 1.8-2.8. This parameter adjustment ensures proper flow characteristics during injection molding, enabling the resin to fill the mold cavity uniformly and bond smoothly with the polyester outer layer, thereby achieving high transparency and excellent interface quality without complicating the manufacturing process.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20250136316A1Multilayer container, method for producing two-layer preform, and method for producing the multilayer container
Publication Date: 2025.05.01 MITSUBISHI GAS CHEM CO INC
  • US20250136316A1 patent drawing

AI summary

To provide a multilayer container including a two-color molding article e, a method for producing a two-layer preform, and a method for producing the multilayer container. The multilayer container including a two-color molding article, the two-color molding article including: an outer layer containing a polyester resin; and an inner layer containing a polyamide resin and being in contact with the outer layer, wherein the polyamide resin has a relative viscosity of 1.8 to 2.8.