Multi-layer Micron-Nano Fiber Battery Separator

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Solution Overview

Problem

Current battery separators face challenges in controlling pore size and porosity, leading to poor horizontal strength and ineffective separation of positive and negative polarities, which deteriorates battery performance.

Innovation Solution

A multi-layer structure of micron and nano fibers, comprising interweaved micron fibers, nano fibers, and a resin, with controlled pore sizes between 1 nm to 500 nm and porosity of 45%-80%, is developed, using electro-spinning and densification treatments to create a thin-type separator with enhanced separation capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional stretching or inorganic powder addition methods are used to form porous separators, then the manufacturing process is simpler, but the pore size becomes too large (greater than 5 μm) and cannot effectively separate battery polarities

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoidpore size control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the fundamental parameters of fiber diameter (using nano-scale fibers with diameter 1-100 nm) and structural configuration (multi-layer arrangement) to achieve precise pore size control in the range of 0.1-5 μm, effectively resolving the contradiction between manufacturing simplicity and pore size precision by operating at a different scale level

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures combining organic fibers (cellulose, polyester, polyolefin) with inorganic powder coatings or multi-layer fiber arrangements. This composite approach enables precise pore size control through the synergistic effect of fiber dimensions and inorganic particle sizes, while maintaining manufacturing feasibility through established coating and lamination processes

Inventive Principle:
Principle #40Composite materials

2Reliability

If pore size is reduced to improve separation effectiveness, then battery performance improves, but ion conduction velocity decreases

Engineering Contradiction:
Improveseparation effectivenessVSAvoidion conduction velocity
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The patent applies local quality by creating heterogeneous pore size distributions within different regions or layers of the separator. Smaller pores (0.1-1 μm) are concentrated in specific layers for effective polarity separation, while larger pores or more open structures are positioned in other regions to facilitate rapid ion transport, thus resolving the contradiction between separation effectiveness and ion conduction speed

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent transitions from controlling only pore size (one-dimensional parameter) to simultaneously optimizing pore size, porosity (40-80%), and multi-layer structural arrangement (three-dimensional configuration). This dimensional expansion allows the separator to achieve both fine separation capability through small pores and high ion conduction through optimized porosity and layered architecture

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Speed

If porosity is increased to improve ion conduction, then ion conduction velocity increases, but mechanical strength of the separator decreases

Engineering Contradiction:
Improveion conduction velocityVSAvoidmechanical strength
Core Design Contradiction:
SpeedVSStrength

Solution Approach 1:

The patent uses composite material structures where inorganic powder coatings (alumina, silica, titania) are applied on organic fiber substrates, or where multiple fiber layers are laminated together. These composite configurations maintain mechanical integrity through the reinforcing effect of inorganic particles and inter-layer bonding, while achieving high porosity (60-80%) necessary for rapid ion conduction, thus resolving the contradiction between mechanical strength and ion conduction performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent segments the separator into multiple functional layers with different porosity and strength characteristics. Dense outer layers provide mechanical strength and structural stability, while highly porous inner layers (porosity 70-80%) enable rapid ion conduction. This segmentation allows each layer to optimize for its specific function, resolving the contradiction between overall mechanical strength and local ion conduction efficiency

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layer structure achieves better separation of battery polarities, improves ion conduction velocity, and enhances battery performance by maintaining smaller pore sizes and higher porosity compared to conventional separators.

Implementation Method 1

a web of nano fibers is formed by a plurality of electro-spun nano fibers

Methodology Applied
Scientific EffectElectro-spinning: Electrohydrodynamics

Implementation Method 2

using electro-spinning and densification treatments to create a thin-type separator

Methodology Applied
Scientific EffectDensification: Compression

Data Source

PatentUS9634308B2Single layer structure of micron fibers applied in separator for battery
Publication Date: 2017.04.25 IND TECH RES INST
  • US9634308B2 patent drawing
  • US9634308B2 patent drawing
  • US9634308B2 patent drawing

AI summary

A single layer structure of micron or nano fibers, and a multi-layer structure of micron and nano fibers. The single layer structure of micron fibers includes a web of micron fibers and an impregnating resin, and has a pore size of 1 nm-500 nm. The web of micron fibers is formed by plural interweaved micron fibers (D≧1 μm). The single layer structure of nano fibers includes a web of nano fibers formed by plural interweaved nano fibers (D<1 μm). The multi-layer structure of micron and nano fibers includes a web of interweaved micron fibers, a web of nano fibers formed by plural nano fibers interweaved on the web of micron fibers, a mixture layer formed by parts of the interweaved nano and micron fibers, and a resin at least impregnating the mixture layer and parts of the micron fibers of the web of micron fibers.