Multilayer 3D Printing Filament for Warpage Control

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Solution Overview

Problem

Fused deposition modeling (FDM) three-dimensional printers face challenges with warpage and dimensional accuracy due to temperature control issues and instability in multilayer filament production, leading to difficulties in achieving intended properties and functions in three-dimensional shaped objects.

Innovation Solution

A three-dimensional modeling material with a multilayer structure comprising specific thermoplastic resins having different shear storage elastic moduli and crystallization temperatures, used in a core-sheath filament design, which allows for improved interlayer adhesion and heat resistance without precise temperature control, and a nozzle mechanism for stacking molten resins to form a multilayer structure during extrusion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If ABS resin or PP is used for heat resistance and strength, then the shaped article has good mechanical properties, but warpage occurs during modeling and dimensional accuracy deteriorates

Engineering Contradiction:
Improveheat resistance and strengthVSAvoiddimensional accuracy
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent uses a multilayer filament structure combining ABS resin (for heat resistance and strength) with PLA resin or other materials (for low warpage). This composite approach allows the final object to simultaneously achieve high strength from the ABS layer and dimensional accuracy from the low-warpage layer, resolving the contradiction between mechanical properties and manufacturing precision

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The filament is divided into multiple functional layers: an outer layer with low warpage characteristics and an inner core layer with high strength characteristics. This segmentation allows each layer to perform its specific function independently, with the outer layer controlling dimensional stability and the inner layer providing structural strength

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If temperature of modeling area is precisely controlled to prevent warpage, then dimensional accuracy is improved, but the three-dimensional printer becomes large and expensive

Engineering Contradiction:
Improvedimensional accuracyVSAvoidtemperature control system complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The filament material itself provides the warpage prevention function through its composition and multilayer structure, eliminating the need for complex external temperature control systems. The material's inherent properties (low coefficient of thermal expansion in certain layers) enable dimensional accuracy without requiring sophisticated environmental control infrastructure

Inventive Principle:
Principle #25Self-service

3Manufacturing precision

If multilayer filament structure is used to prevent warpage, then dimensional accuracy is improved, but it is difficult to appropriately form the filament due to unstable ejection and diameter control

Engineering Contradiction:
Improvedimensional accuracyVSAvoidfilament production ease
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent optimizes specific parameters including the viscosity ratio between layers (outer layer viscosity ≥ 0.8 times inner layer viscosity), layer thickness ratios, and extrusion temperatures to ensure stable multilayer filament formation. These parameter adjustments enable reliable co-extrusion while maintaining the functional multilayer structure

Inventive Principle:
Principle #35Parameter changes

4Adaptability or versatility

If multilayer structure is used to impart specific functions to different portions, then adaptability is improved, but interlayer adhesion becomes difficult to control due to viscosity differences

Engineering Contradiction:
Improvefunctional versatilityVSAvoidinterlayer adhesion
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent carefully controls the viscosity relationship between layers (outer layer viscosity ≥ 0.8 times inner layer viscosity) and adjusts extrusion parameters to ensure proper interlayer adhesion. This parameter optimization allows different resins with varying properties to be combined while maintaining reliable bonding between layers

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution prevents warpage and enhances heat resistance and strength of three-dimensional objects, enabling high-quality industrial applications without the need for precise temperature control and allowing for varied resin combinations to impart specific functions to intended object portions.

Implementation Method 1

a raw material in the form of a filament formed of a thermoplastic resin is first inserted into an extrusion head and continuously extruded from a nozzle portion provided in the extrusion head onto an X-Y plane substrate in a chamber while being heat-fused

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

The extruded resin is deposited on a previously deposited resin stack and fused thereto. As the extruded resin is cooled, it is integrated with the previously deposited resin stack and solidified

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

As the extruded resin is cooled, it is integrated with the previously deposited resin stack and solidified

Methodology Applied
Scientific EffectCooling: Cooling

Data Source

PatentUS11491707B2Material for three-dimensional modeling, filament for three-dimensional modeling, roll of the filament, and cartridge for three-dimensional printer
Publication Date: 2022.11.08 MITSUBISHI CHEM CORP
  • US11491707B2 patent drawing
  • US11491707B2 patent drawing
  • US11491707B2 patent drawing

AI summary

Provided is a three-dimensional modeling material used for a fused deposition modeling three-dimensional printer. The three-dimensional modeling material has a multilayer structure and contains, in respective different layers, a thermoplastic resin (A) having a shear storage elastic modulus (G′) of 1.00×107 Pa or less as measured at 100° C. and 1 Hz and a thermoplastic resin (B) having a shear storage elastic modulus (G′) of more than 1.00×107 Pa as measured at 100° C. and 1 Hz.