Multilayer Film with Surfactant Properties for Detergent Packaging

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Solution Overview

Problem

Current polymer films used for packaging detergents and cleaning agents do not contribute actively to the washing or cleaning process and lack multifunctional properties such as dispersing, deposit-inhibiting, and surfactant properties, which are essential for enhanced cleaning performance.

Innovation Solution

A multilayer film is developed with at least one layer composed of a polymer composition obtained by radical polymerization of α,β-ethylenically unsaturated mono- and dicarboxylic acids, their salts, and anhydrides in the presence of a polyether component, providing dispersing, emulsifying, and surfactant properties that actively participate in the washing process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If polyvinyl alcohol films are used for packaging detergents, then the films dissolve and release ingredients, but the films do not contribute actively to washing or cleaning performance

Engineering Contradiction:
Improvepackaging functionVSAvoidcleaning performance contribution
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent applies multi-functionality by developing polymer films that simultaneously serve as packaging material and active cleaning agent. The film contains polymer chains with carboxylic acid groups that provide both packaging function (encapsulation, controlled release) and cleaning function (surfactant properties, dispersing, deposit-inhibiting), eliminating the need for separate functional components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the packaging function and cleaning function into a single integrated material system. The polymer film combines structural integrity for packaging with active cleaning properties, merging what were previously separate functions (packaging material + cleaning agent) into one multifunctional component.

Inventive Principle:
Principle #5Merging (Combining)

2Ease of operation

If polymer films are used for detergent packaging, then ingredients are released, but the films lack active contribution to washing and cleaning

Engineering Contradiction:
Improveingredient releaseVSAvoidwashing performance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The polymer film is designed to perform multiple functions: it acts as the packaging barrier, controls ingredient release through its solubility and degradation, and simultaneously provides active cleaning performance through its surfactant and dispersing properties, eliminating the need for separate functional additives.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The film is self-functional, meaning it provides both packaging and cleaning functions without requiring external additives or separate components. The polymer itself possesses the necessary active ingredients and properties to contribute to washing performance while maintaining its packaging function.

Inventive Principle:
Principle #25Self-service

3Device complexity

If conventional polymer films are used, then packaging is provided, but multifunctional properties like dispersing and surfactant properties are lacking

Engineering Contradiction:
Improvefilm structureVSAvoidcleaning functionality
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The patent employs composite material strategies by incorporating multiple functional groups and properties into a single polymer film system. The film combines structural polymer matrix with functional groups (carboxylic acid, surfactant moieties) to achieve both packaging integrity and multifunctional cleaning capabilities in one material.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polymer film is designed to perform multiple functions: it acts as the packaging barrier, controls ingredient release through its solubility and degradation, and simultaneously provides active cleaning performance through its surfactant and dispersing properties, eliminating the need for separate functional additives.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer film enhances washing and cleaning performance by releasing ingredients in a controlled manner, stabilizing embedded ingredients, and maintaining stability against external influences, making it suitable for various detergent and cleaning agent formulations.

Implementation Method 1

a polymer composition which is obtainable by radical polymerization of a monomer composition which contains at least one monomer A) which is selected from α,β-ethylenically unsaturated Mono- and dicarboxylic acids, salts of α,β-ethylenically unsaturated mono- and dicarboxylic acids, anhydrides of α,β-ethylenically unsaturated mono- and dicarboxylic acids and mixtures thereof, the radical polymerization taking place in the presence of at least one polyether component

Methodology Applied
Scientific EffectRadical polymerization: Photopolymerisation

Data Source

PatentEP3555153B1Multi-layer films, method for its manufacture and its use
Publication Date: 2020.12.09 BASF SE
  • EP3555153B1 patent drawing
  • EP3555153B1 patent drawing
  • EP3555153B1 patent drawing

AI summary

The present invention relates to a multi-layered film comprising at least one layer having a polymer composition or consisting of a polymer composition, obtainable by radical polymerization of a monomer composition, which contains at least one monomer A), which is selected using α,β-ethylenically unsaturated mono and dicarboxylic acids, salts of an α,β-ethylenically unsaturated mono and dicarboxylic acid, anhydrides of α,β-ethylenically unsaturated mono and dicarboxylic acids and mixtures thereof, wherein the radical polymerization takes place in the presence of at least one polyether component. The invention further relates to a method for producing such a multi-layered film, different uses of said type of multi-layered film and specifically to a covering or coating for a washing, cleaning or dishwasher agent portion which comprises such a multi-layered film or consists thereof. The invention also relates to washing, cleaning or dishwasher agents which have such a multi-layered film.