Multilayer Hard Coating for Cutting Tool Chipping Resistance

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Solution Overview

Problem

Conventional hard-coated cutting tools with aluminum nitride coatings suffer from low chipping resistance and coating adhesion due to coarse crystal grain structures, leading to short tool lives during severe cutting operations.

Innovation Solution

A hard coating comprising a lower fcc-based titanium aluminum nitride layer and an upper hcp-based aluminum nitride layer with a columnar crystal structure, where the upper layer has an average transverse cross section diameter of 0.05-0.6 µm and a specific X-ray diffraction peak ratio, enhancing interlayer adhesion and chipping resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a single-composition starting material gas containing AlCl3 gas and NH3 gas is introduced into a CVD furnace, then aluminum nitride coating is formed, but the coating has a coarse crystal grain structure with low chipping resistance and coating adhesion

Engineering Contradiction:
Improvecoating adhesionVSAvoidchipping resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The coating is divided into two distinct layers: a lower layer with fcc-based titanium aluminum nitride and an upper layer with hcp-based aluminum nitride. This segmentation allows each layer to have optimized properties - the lower layer provides strong adhesion to the substrate while the upper layer provides excellent chipping resistance, resolving the contradiction between coating adhesion and chipping resistance

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite coating structure combining two different material systems (titanium aluminum nitride and aluminum nitride) with different crystal structures (fcc and hcp). This composite approach leverages the complementary strengths of each material - titanium aluminum nitride for adhesion and aluminum nitride for hardness and chipping resistance - thereby simultaneously improving both coating adhesion and chipping resistance

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If aluminum nitride coating with coarse crystal grain structure is formed, then coating can be applied, but tool life is short due to low chipping resistance

Engineering Contradiction:
Improvecoating formationVSAvoidtool life
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The coating is segmented into two layers with different functions. The upper layer uses fine columnar crystals (0.05-0.6 µm diameter) with hcp structure to provide excellent chipping resistance and extended tool life, while still allowing for practical coating formation through CVD process

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the crystal grain size parameter from coarse (conventional) to fine (0.05-0.6 µm diameter columnar crystals), and controls the crystal structure (hcp with specific XRD peak ratio Ia(002)/Ia(100) ≥ 6). These parameter changes significantly improve chipping resistance and tool life while maintaining manufacturability through controlled CVD deposition

Inventive Principle:
Principle #35Parameter changes

3Productivity

If fusion and peeling of work components occurs during cutting, then cutting operation continues, but hard coating peels and chips resulting in short tool life

Engineering Contradiction:
Improvecutting operation continuityVSAvoidcoating adhesion
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The lower layer of fcc-based titanium aluminum nitride is formed first as a preliminary layer before the upper aluminum nitride layer. This preliminary layer acts as a strong bonding interface between the substrate and the upper coating layer, preventing coating peeling during cutting operations and maintaining coating adhesion under severe cutting conditions

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The composite structure with titanium aluminum nitride lower layer and aluminum nitride upper layer creates a gradient of properties that resists both adhesion (through the titanium aluminum nitride layer) and chipping (through the aluminum nitride layer), thereby maintaining coating integrity and adhesion during continuous cutting operations

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed hard coating structure significantly improves chipping resistance and coating adhesion, resulting in longer tool life and reduced peeling during cutting operations.

Implementation Method 1

formed by a thermal CVD method

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

a ratio of an X-ray diffraction peak value Ia(002) of (002) planes to an X-ray diffraction peak value Ia(100) of (100) planes

Methodology Applied
Scientific EffectX-ray diffraction: X-Ray

Data Source

PatentEP3483302B1Hard coating-covered tool, and method for producing
Publication Date: 2022.03.16 MOLDINO TOOL ENG LTD
  • EP3483302B1 patent drawingFigure 1(a)~1(b)
  • EP3483302B1 patent drawingFigure 2~3
  • EP3483302B1 patent drawingFigure 4~5

AI summary

A hard coating comprising a lower layer formed by an fcc-based titanium aluminum nitride coating, and an upper layer formed by an aluminum nitride coating having an hep crystal system, the upper layer having a columnar crystal structure, the columnar crystals having an average transverse cross section diameter of 0.05-0.6 µm, and a ratio of an X-ray diffraction peak value Ia(002) of (002) planes to an X-ray diffraction peak value Ia(100) of (100) planes in the upper layer meeting the relation of Ia(002)/Ia(100)≥6.