Multilayer Hard Coating via CVD for Wear Resistance

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Solution Overview

Problem

Existing surface coated members face issues with impurities in hard coatings formed by PVD methods, leading to distortion and reduced service life due to thermal fatigue, which affects wear resistance and reliability during high-speed metal working.

Innovation Solution

A method involving a CVD process to form a multilayer hard coating structure with alternating layers of Ti and Al compounds, including an intermediate layer, which enhances adhesion and thermal stability, reducing distortion and improving wear resistance and thermal shock resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a PVD method is used to form a hard coating, then the coating can be formed with Ti and Al materials, but impurities and droplets are incorporated into the coating causing distortion and reduced service life

Engineering Contradiction:
Improveservice lifeVSAvoidimpurities and droplets
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces the PVD (Physical Vapor Deposition) mechanical/physical process with a CVD (Chemical Vapor Deposition) chemical process. In CVD, titanium and aluminum chlorides react chemically with ammonia or nitrogen-containing gases to form TiN and AlN coatings through chemical reactions, eliminating the mechanical ejection and condensation process that generates droplets and impurities in PVD methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental deposition mechanism from physical vapor deposition to chemical vapor deposition. This parameter change transforms the coating formation process from a physical ejection-condensation process to a chemical reaction-deposition process, thereby eliminating the generation of metallic droplets and impurities that occur in PVD methods.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If a single-layer TiAlN coating is used, then the coating process is simple, but the coating lacks sufficient adhesion and thermal stability under high-speed working conditions

Engineering Contradiction:
Improvecoating process simplicityVSAvoidadhesion and thermal stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent divides the single-layer TiAlN coating into multiple alternating layers of TiN and AlN. This segmentation creates a multilayer structure where each layer contributes different properties: TiN layers provide hardness and wear resistance, while AlN layers provide thermal stability and oxidation resistance. The layered structure also improves adhesion through intermediate composition layers.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent creates a composite coating structure by alternating TiN and AlN layers. This composite material approach combines the advantages of both materials: TiN contributes high hardness and wear resistance, while AlN contributes thermal stability and oxidation resistance, resulting in a coating with superior overall performance under high-speed working conditions.

Inventive Principle:
Principle #40Composite materials

3Productivity

If high-speed working is performed with surface coated members, then productivity increases, but the cutting edge is exposed to high-temperature and high-pressure environment reducing service life

Engineering Contradiction:
Improveworking speedVSAvoidservice life
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies different material compositions to different layers of the coating to address specific local requirements. The TiN layers provide local hardness and wear resistance at the cutting edge surface, while the AlN layers provide local thermal stability and oxidation resistance deeper in the coating structure, allowing the coating to withstand high-temperature and high-pressure environments during high-speed working.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The alternating TiN and AlN layered structure creates a composite material system that simultaneously provides wear resistance from TiN and thermal stability from AlN, enabling the coating to maintain its protective function under the combined high-temperature and high-pressure conditions encountered during high-speed metal working, thereby extending service life while maintaining high productivity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a surface coated member with improved wear resistance, welding resistance, and thermal shock resistance, leading to increased stability and extended service life, even under harsh high-speed working conditions.

Implementation Method 1

at least one layer among the layers is formed by a CVD method

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

the composition thereof is changed continuously with nitride, carbide, carbonitride, or boride of two or more kinds of elements selected from group 4, 5, 6 elements, Al, and Si

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentEP2939769B1Manufacturing method for surface coated member
Publication Date: 2019.05.08 SUMITOMO ELECTRIC HARDMETAL CORP
  • EP2939769B1 patent drawingFigure 1
  • EP2939769B1 patent drawingFigure 2
  • EP2939769B1 patent drawing

AI summary

A surface coated member having improved stability and a longer service life is provided. The surface coated member of the present invention includes a base member and a hard coating formed on a surface thereof. The hard coating is constituted of one or more layers. At least one of the layers is formed by a CVD method and includes a multilayer structure having a first unit layer and a second unit layer being layered alternately. The first unit layer includes a first compound containing Ti and one or more kind of element selected from the group consisting of B, C, N, and O. The second unit layer includes a second compound containing Al and one or more kind of element selected from the group consisting of B, C, N, and O.