Multilayer Gasketed Membrane-Electrode Assembly for Fuel Cell Sealing

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Solution Overview

Problem

Conventional fuel cell systems face challenges in preventing gas leakage and mixing due to the high cost of electrolyte membranes and the complexity of mass production, particularly in the assembly process where gaskets directly contact the membranes, requiring materials resistant to acidity and suitable for continuous manufacturing.

Innovation Solution

A gasketed membrane-electrode assembly is developed using multilayered films with an elastic layer, adhesive layer, and support layer, where the gasket is united with the polymer electrolyte membrane using an adhesive layer, reducing the need for expensive electrolyte membranes and simplifying the manufacturing process by allowing various material selections for each layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the electrolyte membrane is used as the circumferential part of the membrane-electrode assembly, then gas leakage is prevented, but the cost of the fuel cell increases significantly

Engineering Contradiction:
Improvegas leakage preventionVSAvoidcost of electrolyte membrane
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The circumferential part of the membrane-electrode assembly is divided into two functional zones: the electrode area where the electrolyte membrane is retained for electrochemical reactions, and the peripheral sealing area where a gasket made from cost-effective materials performs the gas leakage prevention function. This segmentation allows each component to be optimized for its specific function while reducing overall cost.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The gasket is made from inexpensive materials such as halogenated resin or elastomers that do not require the same chemical resistance and durability as the electrolyte membrane. While these materials are less expensive, they are designed to be replaced periodically, hence the term 'cheap short-living objects'. This approach significantly reduces the cost of the fuel cell while maintaining reliable gas sealing during the operational lifecycle.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Device complexity

If the gasket directly contacts the electrolyte membrane, then assembly is simplified, but the gasket material must be limited to halogenated resin due to acidity resistance requirements

Engineering Contradiction:
Improveassembly processVSAvoidgasket material selection
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

An intermediary layer or design approach is introduced where the gasket seals against the frame or housing rather than directly contacting the acidic electrolyte membrane. This intermediary arrangement allows the gasket to be made from a broader range of materials including elastomers and other polymers that would otherwise be corroded by direct contact with the membrane, thus expanding material selection flexibility while maintaining assembly simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If the molding method is used to manufacture the electrolyte membrane and gasket assembly, then manufacturing is simplified, but continuous mass production is not suitable

Engineering Contradiction:
Improvemanufacturing processVSAvoidcontinuous mass production capability
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The manufacturing process is segmented into separate steps for producing the membrane-electrode assembly and the gasket, allowing each component to be manufactured using optimized processes. The membrane-electrode assembly can be produced using conventional molding or lamination methods, while the gasket can be manufactured separately using injection molding or extrusion processes suitable for continuous mass production. These pre-manufactured components are then assembled together, enabling high-volume production while maintaining manufacturing simplicity.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively decreases gas leakage and facilitates mass production of fuel cells by providing a cost-effective and easily handled assembly process, ensuring sufficient sealing and durability while maintaining the integrity of the polymer electrolyte membrane.

Implementation Method 1

a gasket film united with a polymer electrolyte membrane with an adhesive layer

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

a polymer membrane where hydrogen ions are transferred

Methodology Applied
Scientific EffectIon conduction: Fast Ion Conductor

Implementation Method 3

a direct current power generator that transforms chemical energy of a fuel into electrical energy through an electrochemical reaction

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 4

an electrode where a methanol solution or a fuel such as hydrogen reacts with air through an electrochemical catalytic reaction

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS7544219B2Gasketed membrane-electrode-assembly and fuel cell system employing the same
Publication Date: 2009.06.09 LG CHEM LTD
  • US7544219B2 patent drawing
  • US7544219B2 patent drawing
  • US7544219B2 patent drawing

AI summary

The present invention relates to a gasketed membrane-electrode assembly comprising gaskets arranged on each side of a membrane-electrode assembly including a cathode, an anode, and a polymer electrolyte membrane, in which the gaskets are multilayered films comprising an elastic layer and an adhesive layer formed on each side of a support layer. According to the present invention, the gasket film can be united with the polymer electrolyte membrane, and the leakage of fuel gas and oxidizing gas decreases on operation of a fuel cell. In addition, various materials can be selected for each layer of the gasket. Thus, it can be suitable for mass production of a polymer fuel cell due to its simple manufacturing process.