Multilayer Nitride Hard Coating Composition for Wear Resistance

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current hard coatings for cutting tools and wear-resistant components lack sufficient wear resistance and longevity, necessitating the development of more effective multilayer nitride coatings.

Innovation Solution

A hard coating comprising a first layer of titanium aluminum nitride and a second layer with alternating sublayers of titanium silicon nitride and titanium aluminum nitride, where the composition of titanium aluminum nitride is (TixAl1-x)N with 0.4≦x≦0.6 and titanium silicon nitride is (TiySi1-y) with 0.85≦y≦0.98, with a specific sum of x and y in the range of 1.38 to 1.46, to enhance wear resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional hard coatings are used to improve wear resistance, then hardness is increased, but toughness and longevity are insufficient

Engineering Contradiction:
ImprovehardnessVSAvoidwear resistance and longevity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by creating a multilayer coating structure combining titanium aluminum nitride (TiAlN) and titanium silicon nitride (TiSiN) layers. Each layer contributes different properties: TiAlN provides hardness and oxidation resistance, while TiSiN provides toughness and wear resistance. The composite structure synergistically combines these properties to achieve both high hardness and improved wear resistance/longevity, resolving the contradiction between strength and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies segmentation by dividing the coating into multiple alternating layers of TiAlN and TiSiN with specific thicknesses (TiAlN: 5-20 nm, TiSiN: 3-10 nm). This segmented multilayer structure allows each layer to perform its specialized function while the overall structure achieves enhanced wear resistance and longevity compared to conventional single-layer coatings, resolving the contradiction between hardness and reliability.

Inventive Principle:
Principle #1Segmentation

2Reliability

If multilayer coatings with alternating lubricating and hard layers are used, then wear resistance is improved, but the coating complexity increases

Engineering Contradiction:
Improvewear resistanceVSAvoidcoating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the thickness parameters of each layer (TiAlN: 5-20 nm, TiSiN: 3-10 nm) and the compositional parameters (aluminum content 30-70 at%, silicon content 10-50 at%). These controlled parameter variations optimize the balance between wear resistance and structural complexity, achieving improved reliability without excessive complexity through defined parameter ranges rather than arbitrary values.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high aluminum content is used in TiAlN layers, then oxidation resistance is improved, but hardness decreases

Engineering Contradiction:
Improveoxidation resistanceVSAvoidhardness
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies local quality by creating spatial variation in aluminum content within the TiAlN layers, with different regions having different aluminum concentrations (30-70 at%). This local quality variation allows certain regions to provide oxidation resistance while other regions maintain hardness, and the alternating TiSiN layers provide additional hardness compensation, resolving the contradiction between oxidation resistance and hardness through localized property optimization.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The described hard coating significantly improves wear resistance and tool life by optimizing the combined amount of aluminum and silicon in the sublayer groups, outperforming conventional coatings in both hardness and toughness.

Implementation Method 1

a first sublayer of titanium silicon nitride and a second sublayer of titanium aluminum nitride... significantly improves wear resistance and tool life by optimizing the combined amount of aluminum and silicon... outperforming conventional coatings in both hardness and toughness

Methodology Applied
Scientific EffectHardness:

Data Source

PatentUS8568866B2Multilayer nitride hard coatings
Publication Date: 2013.10.29 KENNAMETAL INC
  • US8568866B2 patent drawing
  • US8568866B2 patent drawing
  • US8568866B2 patent drawing

AI summary

A wear resistant multilayer nitride hard coating for substrates. The hard coating includes a first layer of titanium aluminum nitride and a second layer comprising a plurality of sublayer groups. Each sublayer group includes a first sublayer of titanium silicon nitride and a second sublayer of titanium aluminum nitride. The composition of the titanium aluminum nitride, both in the first layer and in the sublayer groups, is (TixAl1-x)N, wherein 0.4≦x≦0.6. The composition of the titanium silicon nitride sublayers is (TiySi1-y)N, wherein 0.85≦y≦0.98, and all of the silicon is in solid solution in the titanium silicon nitride such that no silicon phase or silicon nitride phase exists in this sublayer. The combined amount of aluminum and silicon present in the sublayer groups being narrowly controlled such that the sum of x and y is in the range of 1.38 to 1.46.