Multilayer Overlay System for Superalloy Thermal Protection

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Solution Overview

Problem

Existing multilayer overlay systems for turbine engine components face issues with thermal stability, corrosion resistance, and surface finish defects, particularly at elevated temperatures, leading to potential failure and reduced aerodynamic efficiency.

Innovation Solution

A multilayer overlay system comprising a basecoat layer with metal or metal oxide pigment particles dispersed in a phosphate-based binder, followed by a second layer with chromium oxide pigment particles having a narrow particle size distribution and optimized surface area, applied to a thickness of 0.1 to 1.0 mil, enhancing thermal and corrosion stability and surface finish.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a prior art multilayer overlay system is used for lower service temperatures, then effective protection is provided up to 1200°F, but the system is prone to cracking and delamination at elevated operating temperatures (≥1300°F)

Engineering Contradiction:
Improveprotection effectivenessVSAvoidoperating temperature range
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent modifies the chemical composition parameters of the overlay system by incorporating specific metal powders (aluminum, nickel, cobalt) and metal oxide particles in controlled ratios, along with organic vehicle and curing agents. This compositional parameter change enables the coating to maintain structural integrity and protective function at elevated temperatures up to 1400°F, resolving the temperature limitation of prior art systems

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite overlay material combining multiple metal powders (aluminum, nickel, cobalt) with metal oxide particles dispersed in a phosphate-based binder. This composite structure provides synergistic effects where the metal powders offer thermal stability and the metal oxides provide corrosion resistance, enabling reliable protection at temperatures where single-material systems fail

Inventive Principle:
Principle #40Composite materials

2Reliability

If intermediate layers are applied to provide protection, then coverage is achieved, but visible particle inclusions create a gritty coating appearance that becomes more pronounced after seal coat application

Engineering Contradiction:
Improveprotection coverageVSAvoidsurface finish quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies different functional layers with specific compositions: the base layer provides protection coverage while the intermediate layer uses finely dispersed metal oxide particles (0.1-10 micrometers) to achieve both coverage and smooth surface finish. This local differentiation of layer properties allows the intermediate layer to simultaneously provide protection and eliminate the gritty appearance problem

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent controls the particle size parameter of metal oxide particles within 0.1-10 micrometers and optimizes the concentration of metallic particles (5-50 weight percent) to achieve proper dispersion. This parameter control ensures adequate protection coverage while preventing visible particle inclusions that cause gritty appearance, resolving the surface finish quality issue

Inventive Principle:
Principle #35Parameter changes

3Temperature

If the overlay system is designed for thermal protection, then high temperature resistance is achieved, but oxidation and corrosion reactions at the surface cause metal wastage and loss of wall thickness

Engineering Contradiction:
Improvehigh temperature resistanceVSAvoidmetal wastage
Core Design Contradiction:
TemperatureVSLoss of substance

Solution Approach 1:

The patent introduces metal oxide particles (such as chromium oxide, aluminum oxide) as intermediary protective layers between the metal substrate and the corrosive environment. These metal oxides form stable, adherent surfaces that act as barriers to oxidation and corrosion, preventing direct attack on the metal substrate and eliminating the need for periodic removal of degraded material

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite structure where metal powders provide thermal stability and metal oxide particles provide corrosion and oxidation resistance. This composite material design allows the overlay system to simultaneously withstand high temperatures and prevent surface degradation, eliminating metal wastage and wall thickness loss even in severe corrosive environments

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system demonstrates improved thermal stability, corrosion resistance, and surface finish characteristics, reducing defects and maintaining integrity at high temperatures, thus extending the lifespan and performance of turbine engine components.

Implementation Method 1

a basecoat layer formed by applying a slurry comprising metal oxide pigment particles dispersed in a phosphate-based binder

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

The multilayer overlay system of the present invention demonstrates improved thermal and corrosion stability

Methodology Applied
Scientific EffectThermal stability: Thermal Insulation

Implementation Method 3

corrosion resistance, and surface finish characteristics, reducing defects and maintaining integrity at high temperatures

Methodology Applied
Scientific EffectCorrosion resistance: Oxidation

Data Source

PatentUS9598775B2Multilayer overlay system for thermal and corrosion protection of superalloy substrates
Publication Date: 2017.03.21 PRAXAIR ST TECHNOLOGY INC
  • US9598775B2 patent drawing
  • US9598775B2 patent drawing
  • US9598775B2 patent drawing

AI summary

A high surface finish, thermally stable, multilayer slurry-based overlay system suitable for use in a severe thermal environment is disclosed. The disclosed embodiments include a basecoat layer formed from a slurry comprising ceramic pigment filled phosphate-based binder, a second layer formed from a slurry comprising metal oxide pigment or ceramic oxide pigment filled phosphate-based binder, and an optional seal coat layer formed from a phosphate-based binder substantially free of pigments.