Multilayer Plastic Bottles with Foamed Inner Layer for Recyclability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Plastic bottles with mineral fillers face limitations in recycling due to density issues, as high filler loadings cause them to sink in floatation tanks, restricting cost reductions and environmental benefits from reduced petrochemical resin use.

Innovation Solution

A multilayer plastic container design incorporating foamed polyolefin layers to offset the increased density of mineral fillers, maintaining a specific gravity below 1.0, allowing for higher filler loadings while ensuring floatation separation during recycling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If mineral filler loading is increased to reduce petrochemical resin usage, then cost reductions and environmental benefits are achieved, but the specific gravity increases causing the container to sink in floatation tanks during recycling

Engineering Contradiction:
Improvemineral filler loadingVSAvoidspecific gravity
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The container is divided into multiple layers with different compositions. The outer layer contains high mineral filler loading (at least 5% by weight) for cost reduction and environmental benefits, while the inner layer contains foamed polyolefin with lower density. This segmentation allows each layer to serve its specific function while the overall container maintains floatation capability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the container have different material properties tailored to specific functions. The outer layer has high mineral content for economic and environmental advantages, while the inner layer has foamed structure for buoyancy control. This local differentiation resolves the contradiction between filler loading and specific gravity.

Inventive Principle:
Principle #3Local quality

Solution Approach 3:

The container uses a composite structure combining mineral-filled polyolefin in the outer layer with foamed polyolefin in the inner layer. This composite material approach allows the container to simultaneously achieve cost reduction through mineral filler and recyclability through maintained floatation capability.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If mineral filler is added to polyolefin to reduce resin usage, then petrochemical dependency decreases, but the container sinks in floatation separation tanks

Engineering Contradiction:
ImproverecyclabilityVSAvoidfloatation capability
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The container wall is segmented into an outer layer with mineral filler for recyclability and an inner foamed layer for floatation capability. This segmentation allows the container to be both recyclable (through mineral filler content) and floatable (through the inner foamed layer).

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The inner layer is specifically designed with foamed polyolefin to provide local buoyancy that compensates for the overall increased density from mineral filler in the outer layer, ensuring floatation separation works effectively.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If high mineral filler loading is used to reduce polyolefin resin, then cost savings are achieved, but the container structure may compromise strength

Engineering Contradiction:
Improvepolyolefin resin usageVSAvoidcontainer strength
Core Design Contradiction:
Quantity of substanceVSStrength

Solution Approach 1:

The container is segmented into an outer layer with high mineral filler for cost reduction and an inner foamed layer for structural support. The multilayer construction ensures that strength requirements are met while minimizing polyolefin resin usage through strategic material placement.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The composite multilayer structure combines mineral-filled polyolefin with foamed polyolefin to achieve both cost reduction through reduced resin content and maintained structural integrity through the synergistic combination of layers.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer design enables increased mineral filler loadings, reducing polyolefin resin usage while maintaining strength and recyclability, allowing for cost savings and environmental benefits without compromising separation in recycling processes.

Implementation Method 1

The polyolefin of at least one of the layers may be foamed, e.g., a cellular foamed layer including closed cells of a foaming agent within a polyethylene matrix

Methodology Applied
Scientific EffectFoaming: Foam

Implementation Method 2

polyolefin bottles or other containers in the recycling stream being separated from glass, ceramic, polyester, or other materials using floatation separation in a floatation tank

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Data Source

PatentUS11541588B2Multilayer plastic bottles with mineral filler and foamed layer for improved recyclability
Publication Date: 2023.01.03 THE CLOROX CO
  • US11541588B2 patent drawing
  • US11541588B2 patent drawing
  • US11541588B2 patent drawing

AI summary

Plastic containers exhibiting reduced plastic resin usage, while maintaining a specific gravity of below 1.0, so as to allow their quick and easy separation using floatation techniques during recycling. Within a layer or portion some of the plastic resin of the container body may be replaced with an inorganic mineral filler material, while within another layer or portion of the plastic container, the plastic material (e.g., polyethylene, polypropylene) may be foamed. The fraction of mineral filler material that may be included within the polyethylene may thus be increased beyond that previously possible while maintaining the specific gravity below 1.0, by also foaming a layer or portion of the polymeric material, so as to create voids therein. This allows significantly less resin material to be employed, while maintaining strength characteristics of the plastic container so as to be at least comparable to existing plastic containers not including such mineral filler materials.