Multilayer Polyamide Tube for Refrigerant Transport

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Solution Overview

Problem

Current tubular structures for transporting refrigerant fluids in automotive air conditioning fail to meet the requirements of high water permeability and hot burst strength simultaneously, while also needing to be watertight and chemically resistant to refrigerants like R134, R-1234yf, and R-1234ze, and environmentally durable.

Innovation Solution

A multilayer tubular structure comprising a long-chain polyamide outer layer and a polyamide inner layer with specific carbon atom ratios, devoid of continuous fibers, and optionally a short-chain polyamide layer, ensuring at least 50% of the total thickness is comprised by the inner layer for enhanced performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If long-chain polyamides are used, then water permeability is improved, but hot burst strength deteriorates

Engineering Contradiction:
Improvewater permeabilityVSAvoidhot burst strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The tubular structure is divided into multiple layers with different polyamide chain lengths. The inner layer uses long-chain polyamide for water permeability, while the outer layer uses short-chain polyamide for hot burst strength. This segmentation allows each layer to optimize for its specific function without compromise.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite multilayer structure combining different polyamide materials (long-chain and short-chain) in specific configurations. This composite approach integrates the advantageous properties of each material type to achieve overall performance that neither material could provide alone.

Inventive Principle:
Principle #40Composite materials

2Strength

If short-chain polyamides are used, then hot burst strength is improved, but water permeability deteriorates

Engineering Contradiction:
Improvehot burst strengthVSAvoidwater permeability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The tubular structure is divided into multiple layers with different polyamide chain lengths. The inner layer uses long-chain polyamide for water permeability, while the outer layer uses short-chain polyamide for hot burst strength. This segmentation allows each layer to optimize for its specific function without compromise.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite multilayer structure combining different polyamide materials (long-chain and short-chain) in specific configurations. This composite approach integrates the advantageous properties of each material type to achieve overall performance that neither material could provide alone.

Inventive Principle:
Principle #40Composite materials

3Reliability

If multilayer structure is implemented, then chemical resistance and watertight properties are improved, but device complexity increases

Engineering Contradiction:
Improvechemical resistanceVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Each layer of the multilayer structure is designed with specific local properties tailored to its function. The inner layer provides chemical resistance to refrigerants, while outer layers provide mechanical strength and environmental protection. This local quality optimization achieves high reliability without unnecessary complexity throughout the entire structure.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS11338541B2Multilayer tubular structure intended for transporting an air-conditioning fluid
Publication Date: 2022.05.24 ARKEMA FRANCE SA

AI summary

A multilayer tubular structure intended for transporting a heat-transfer fluid, the multilayer tubular structure including: a first layer including at least one long-chain polyamide having between 10 and 15 carbon atoms per nitrogen atom and including at least 50% aliphatic units relative to the sum of the units present in the long-chain polyamide; a second layer including at least one polyamide having between 4 and 9 carbon atoms per nitrogen atom, the polyamide including at least 50% aliphatic units relative to the sum of the units present in the polyamide; an optional layer, the first layer containing no continuous fibres, the second layer being in contact with the transported fluid when an optional layer is not present, and the layer or layers representing at least 50% of the total thickness of the tube.