Multilayer Primer-Surfacer Coating Resolving Stonechip and Bird-Dropping Resistance

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Solution Overview

Problem

Conventional multicoat coatings for automotive finishes lack sufficient bird-dropping resistance, leading to delamination and paint flaking, while also failing to meet stonechip resistance standards.

Innovation Solution

A multicoat coating system comprising a primer-surfacer coat made from a nonaqueous solvent-based coating material with specific polyester formulations, crosslinkers, and fillers/pigments, applied in a method that includes curing steps for each coat, providing enhanced stonechip and bird-dropping resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional primer-surfacer formulations are used, then stonechip resistance is sufficient, but bird-dropping resistance is poor leading to delamination

Engineering Contradiction:
Improvebird-dropping resistanceVSAvoidadhesion stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses a composite binder system comprising at least two different polyesters with distinct glass transition temperatures (one ≥20°C and another ≤10°C). This composite material approach combines the benefits of both polyesters: the higher Tg polyester provides stonechip resistance while the lower Tg polyester maintains flexibility and adhesion, preventing delamination when birds droppings occur. The synergistic interaction between the two polyesters resolves the contradiction between stonechip protection and adhesion stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies parameter changes by carefully controlling the glass transition temperatures of the polyester components and their weight ratios. By adjusting these parameters, the coating achieves an optimal balance: the higher Tg polyester (≥20°C) provides the hardness needed for stonechip resistance, while the lower Tg polyester (≤10°C) ensures the coating remains flexible enough to maintain adhesion under thermal and mechanical stress from bird droppings.

Inventive Principle:
Principle #35Parameter changes

2Strength

If higher glass transition temperature polyester is used, then stonechip resistance improves, but coating flexibility decreases affecting adhesion

Engineering Contradiction:
Improvestonechip resistanceVSAvoidcoating flexibility
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent employs a composite material strategy by combining two polyesters with complementary properties. The first polyester (Tg ≥20°C) contributes to stonechip resistance through its higher crosslink density and rigidity, while the second polyester (Tg ≤10°C) provides flexibility and elongation. Together, they create a coating that is both strong and flexible, resolving the contradiction between strength and ease of operation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by assigning different functional roles to different polyester components within the same coating system. The higher Tg polyester locally provides hardness and chip resistance where needed, while the lower Tg polyester locally provides flexibility and adhesion in areas susceptible to thermal and mechanical stress, achieving both properties simultaneously throughout the coating.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating system achieves excellent stonechip resistance and high bird-dropping resistance, while maintaining a sufficient shelf life for the coating materials, as demonstrated by improved performance in weathering tests.

Implementation Method 1

nonaqueous, solvent-based coating material

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

curing the primer-surfacer coat (II)

Methodology Applied
Scientific EffectCuring:

Data Source

PatentUS10421879B2Multilayer coating with a primer-surfacer of a nonaqueous coating material comprising at least two different polyesters
Publication Date: 2019.09.24 BASF COATINGS GMBH

AI summary

Method for producing a multicoat coating comprises: applying a primer-surfacer coat (I) to an optionally pretreated substrate, curing coat (I), applying a basecoat (II) to coat (I), optionally curing the basecoat (II), applying a clearcoat (III) to basecoat (II), and curing basecoat (II) and/or clearcoat (III), wherein coat (I) is obtained by applying a nonaqueous, solventborne coating material comprising by weight: at least 20% of at least one organic solvent, at least 8% of at least one first polyester (A1), having a glass transition temperature of at least 20° C. and an acid number of 0 to 40 mg KOH/g; at least 8% by weight of at least one second polyester (A2), different from (A1) and having a glass transition temperature of not more than 10° C.; at least one crosslinker (B); and at least 8% of one or more fillers and/or pigments (C).