Multilayer Printed Indicia Adhesion via Curable Polymer Coatings

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Solution Overview

Problem

Existing printed indicia and stencils face issues such as inferior adhesion, interlayer cohesion, and migration of volatile compounds, leading to problems like shrinkage, curling edges, and residue left on surfaces upon removal.

Innovation Solution

A method involving the application of curable compositions comprising polymer powders, plasticizers, and monomers/oligomers, followed by heating and crosslinking, to create a multilayered structure with improved interlayer cohesion and adhesion, using techniques like UV or EB irradiation to form a solid coating with enhanced mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional printing inks and adhesives are used, then the production process is simple, but adhesion and interlayer cohesion are inferior

Engineering Contradiction:
Improveadhesion and interlayer cohesionVSAvoidproduction process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent uses composite materials consisting of polymer powders, plasticizers, monomers, and oligomers combined in specific ratios to create a curable composition that forms strong interlayer bonds. This composite approach enables superior adhesion and interlayer cohesion while maintaining processability through controlled curing mechanisms.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by controlling temperature, time, and chemical composition during the curing process. By adjusting these parameters, the material transitions from a soft, adhesive state to a cured, strong bond state, achieving high strength without excessive process complexity.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If volatile compounds are present in the composition, then the material is easier to process, but migration of volatiles causes shrinkage, curling edges, and residue

Engineering Contradiction:
Improveease of processingVSAvoidmigration of volatile compounds
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent uses parameter changes by carefully controlling temperature profiles during processing and curing. By maintaining temperatures within specific ranges and controlling humidity levels, the material processes easily while minimizing volatile migration that causes defects like shrinkage and curling.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of volatile compounds into a benefit by using controlled evaporation during the curing process. The volatiles are managed through controlled release during curing, transforming what would be a defect into part of the desired curing mechanism, reducing residue and improving final product quality.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Adaptability or versatility

If multiple layers are applied to improve functionality, then the product performance increases, but interlayer cohesion and adhesion deteriorate

Engineering Contradiction:
Improveproduct functionalityVSAvoidinterlayer cohesion and adhesion
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The patent applies homogeneity by ensuring uniform distribution of polymer powders, plasticizers, monomers, and oligomers across multiple layers. This homogeneous composition throughout all layers ensures consistent adhesion and interlayer cohesion, allowing multiple layers to be applied without compromising bond strength.

Inventive Principle:
Principle #33Homogeneity

Solution Approach 2:

The patent uses composite materials with specific ratios of polymer powders, plasticizers, monomers, and oligomers that work synergistically across multiple layers. This composite formulation maintains strong interlayer bonds while enabling enhanced product functionality through multi-layer construction.

Inventive Principle:
Principle #40Composite materials

4Duration of action of stationary object

If conventional materials are used, then the production cost is lower, but long-term strength and endurance are insufficient

Engineering Contradiction:
Improvelong-term strength and enduranceVSAvoidproduction cost
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent employs composite materials with optimized ratios of polymer powders, plasticizers, monomers, and oligomers that provide superior long-term strength and endurance. While the material composition is enhanced, the manufacturing process remains cost-effective through controlled curing and efficient resource utilization.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies preliminary action by pre-mixing and pre-preparing the curable composition with optimal ratios of components before application. This preliminary preparation ensures long-term durability and strength while streamlining the manufacturing process and reducing overall production costs through efficient material utilization.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides long-term strength and endurance, prevents volatile losses, and allows for recycling, resulting in a durable and environmentally friendly multilayered printed indicia or stencil with improved adhesion and dimensional stability.

Implementation Method 1

heating the curable coating composition to a temperature of about 70-about 120° C., to provide a gelled curable coating

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

the plasticizer/monomer/oligomer mixture to be absorbed in the polymer powder to avoid premature polymer curing

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

crosslinking the heated multilayer-coated substrate, by irradiation and/or subjection to heat at a temperature of about 165-about 190° C.

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS10919288B2Method of producing a multilayered product
Publication Date: 2021.02.16 PROCRAFT BV
  • US10919288B2 patent drawing

AI summary

In embodiments, the present invention relates to a method of producing a multilayered printed item, comprising: (a) providing a coating of curable composition comprising a polymer powder, at least one plasticizer, and at least one monomer and/or oligomer, onto the substrate or a thereon previously applied layer or coating; (b) heating the curable coating composition to a temperature of about 70-120° C., to provide a gelled curable coating; (c) providing a coating of curable composition comprising a polymer powder, at least one plasticizer, and at least one monomer and/or oligomer, onto the previously applied layer or coating; (d) heating the other curable as above, to provide second gelled curable coating; (e) before crosslinking is performed, the multilayer-coated substrate formed is heated to a temperature of about 130-160° C.; and (f) crosslinking the heated multilayer-coated substrate, by irradiation and/or subjection to heat at a temperature of about 165-190° C.