Multilayer Polyvinyl Acetal Interlayer for Impact and Acoustic Balance

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Solution Overview

Problem

Poly(vinyl acetal) resin compositions used in safety glass and polymeric laminates face challenges in balancing mechanical, optical, and acoustic properties, with high residual hydroxyl content resins offering impact resistance but poor vibration dampening, and low residual hydroxyl content resins providing good sound attenuation but limited impact resistance across a broad temperature range.

Innovation Solution

A multilayer interlayer comprising two poly(vinyl acetal) resin layers with different plasticizer contents and aldehyde compositions, where one resin layer has a higher glass transition temperature and specific refractive index, and the other has a higher residual hydroxyl content and plasticizer content, optimizing mechanical and optical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If PVB resin compositions having high residual hydroxyl contents and low plasticizer contents are used, then impact resistance is improved, but vibration dampening and sound attenuation performance deteriorate

Engineering Contradiction:
Improveimpact resistanceVSAvoidvibration dampening and sound attenuation performance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention divides the interlayer into multiple resin layers with different compositions. One layer contains high residual hydroxyl content resin for impact resistance, while another layer contains low residual hydroxyl content resin for vibration dampening and sound attenuation. This segmentation allows each layer to specialize in one function, resolving the contradiction between impact resistance and acoustic performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions (layers) of the interlayer are given different local qualities through varying residual hydroxyl content and plasticizer content. The high hydroxyl layer provides mechanical strength where needed, while the low hydroxyl layer provides acoustic damping in its region, allowing the overall structure to achieve both properties simultaneously.

Inventive Principle:
Principle #3Local quality

2Reliability

If PVB resin compositions having lower residual hydroxyl contents and higher amounts of plasticizer are used, then vibration and sound dampening properties are improved, but impact resistance deteriorates

Engineering Contradiction:
Improvevibration and sound dampening propertiesVSAvoidimpact resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The interlayer is segmented into distinct resin layers where one layer is optimized for acoustic performance (low hydroxyl, high plasticizer) and another layer is optimized for mechanical performance (high hydroxyl, low plasticizer). This functional segmentation resolves the contradiction by assigning different roles to different layers.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite interlayer structure combining multiple poly(vinyl acetal) resin layers with different compositions. The composite structure integrates the advantages of both high-hydroxyl resin (impact resistance) and low-hydroxyl resin (acoustic damping) into a single interlayer system.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If a single resin composition is used in the interlayer, then manufacturing simplicity is maintained, but the ability to achieve multiple desirable properties simultaneously deteriorates

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidability to achieve multiple desirable properties
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

Rather than attempting to create a single resin composition that achieves all properties, the invention segments the interlayer into multiple layers, each optimized for specific properties. This approach maintains manufacturing simplicity while achieving versatility, as each layer can be independently formulated and processed using standard lamination techniques.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS10960650B2Poly(vinyl acetal) resin compositions, layers, and interlayers having enhanced properties
Publication Date: 2021.03.30 SOLUTIA INC
  • US10960650B2 patent drawing
  • US10960650B2 patent drawing
  • US10960650B2 patent drawing

AI summary

Resin compositions, layers, and interlayers comprising a poly(vinyl acetal) resin that includes residues of an aldehyde other than n-butyraldehyde are provided. Such compositions, layers, and interlayers can exhibit enhanced or optimized properties as compared to those formulated with comparable poly(vinyl n-butyral) resins.