Multi-Layer Sol-Gel Coating for Solar Glass Durability

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Solution Overview

Problem

Current anti-reflective coatings for solar panels and glass surfaces face challenges with abrasion resistance, soiling resistance, and durability due to chemical and physical interactions with environmental factors, requiring frequent cleaning and suffering from reduced optical performance over time.

Innovation Solution

A sol-gel coating composition using silane precursors, solvents, and optional catalysts is applied to form a durable, hydrophobic, and anti-soiling coating that is abrasion-resistant, maintaining optical performance and adhering strongly to the substrate without cracking, and can be cured at low temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional anti-reflective coatings are applied to glass surfaces, then reflection is reduced and optical performance is improved, but abrasion resistance deteriorates and the coating requires frequent cleaning

Engineering Contradiction:
Improveoptical performanceVSAvoidabrasion resistance
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies a multi-layer composite coating structure where the first layer contains silica particles in a binder matrix, and the second layer contains different silica particle sizes and composition. This composite structure combines the optical benefits of anti-reflective properties with the mechanical benefits of abrasion resistance through the layered composite architecture.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent creates different local properties within the coating by varying silica particle size distribution, composition, and concentration across different layers. The first layer has specific particle characteristics optimized for one function, while the second layer has different characteristics optimized for another function, achieving both optical and mechanical performance in different locations of the same coating system.

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If conventional anti-reflective coatings are exposed to environmental factors, then soiling occurs and cleaning frequency increases, but maintenance costs and time consumption increase

Engineering Contradiction:
Improvesoiling resistanceVSAvoidcleaning time
Core Design Contradiction:
Object-affected harmful factorsVSLoss of time

Solution Approach 1:

The patent creates a coating surface with specific physical and chemical properties that enable self-cleaning functionality. The multi-layer structure with controlled porosity and surface energy allows the coating to resist soiling accumulation and facilitate easy removal of contaminants without requiring intensive manual cleaning, thus reducing maintenance time and effort.

Inventive Principle:
Principle #25Self-service

3Reliability

If multi-layer coatings with different silica particle sizes are applied, then durability and abrasion resistance are enhanced, but manufacturing complexity increases

Engineering Contradiction:
ImprovedurabilityVSAvoidcoating structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the coating into distinct layers, with each layer containing silica particles of specific size ranges and compositions. This segmentation allows for optimized performance in each layer while maintaining overall system durability, and simplifies the manufacturing process by enabling separate preparation and application of each layer with controlled characteristics.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating provides enhanced durability and long-term performance by reducing reflection, scattering, and soiling, increasing solar module efficiency and reducing maintenance needs, while maintaining transparency and mechanical strength across various environmental conditions.

Implementation Method 1

A sol-gel coating composition using silane precursors, solvents, and optional catalysts is applied to form a durable, hydrophobic, and anti-soiling coating

Methodology Applied
Scientific EffectSol-gel process: Gel

Implementation Method 2

The coating compositions are hydrolyzed to provide a sol that can be coated on a substrate from which a gel is formed

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

A sol-gel coating composition using silane precursors, solvents, and optional catalysts is applied to form a durable, hydrophobic, and anti-soiling coating

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 4

Anti-reflective coatings are used in a wide variety of commercial applications ranging from sunglasses, windows, car windshields, camera lenses, solar panels, and architectural systems

Methodology Applied
Scientific EffectAnti-reflective coating effect: Anti-Reflective Coating

Data Source

PatentUS9376593B2Multi-layer coatings
Publication Date: 2016.06.28 FIRST SOLAR INC
  • US9376593B2 patent drawing
  • US9376593B2 patent drawing
  • US9376593B2 patent drawing

AI summary

Disclosed herein are coating materials and methods for applying a top-layer coating that is durable, abrasion resistant, highly transparent, hydrophobic, low-friction, moisture-sealing, anti-soiling, and self-cleaning to an existing conventional high temperature anti-reflective coating. The top coat imparts superior durability performance and new properties to the under-laying conventional high temperature anti-reflective coating without reducing the anti-reflectiveness of the coating. Methods and data for optimizing the relative thickness of the under-layer high temperature anti-reflective coating and the top-layer thickness for optimizing optical performance are also disclosed.