Multilayer Spacer Structure for Magnetic Memory Thermal Stability

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Solution Overview

Problem

Conventional memory devices with thin conductive spacer layers face issues with thermal stability and interlayer mixing during fabrication, leading to weakened anti-ferromagnetic exchange coupling, which affects the performance and reliability of variable resistance elements.

Innovation Solution

The use of a multilayer spacer structure with a thickness greater than conventional Ru single layers, incorporating layers such as [Ru/x]n or [x/Ru]n, where x includes metals, oxides, or nitrides, to enhance thermal stability and prevent intermixing with adjacent magnetic layers, thereby improving anti-ferromagnetic exchange coupling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a thin conductive spacer layer is used, then the device complexity is reduced and manufacturing is easier, but thermal stability deteriorates and interlayer mixing occurs during fabrication

Engineering Contradiction:
Improvespacer layer structureVSAvoidthermal stability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The spacer layer is constructed as a composite structure with alternating layers of Ru (ruthenium) and x (metal, oxide, or nitride). This composite configuration provides thermal stability and prevents interlayer mixing while maintaining the necessary anti-ferromagnetic exchange coupling characteristics, resolving the contradiction between structural simplicity and thermal reliability.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If a thin conductive spacer layer is used, then the device complexity is reduced, but anti-ferromagnetic exchange coupling strength deteriorates

Engineering Contradiction:
Improvespacer layer structureVSAvoidanti-ferromagnetic exchange coupling
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The alternating Ru and x layers in the composite spacer structure are designed to maintain strong anti-ferromagnetic exchange coupling between adjacent magnetic layers. The specific combination of Ru (which provides good conductivity and coupling) with x (metal, oxide, or nitride for stability) ensures that coupling strength is preserved while simplifying the overall device structure.

Inventive Principle:
Principle #40Composite materials

3Reliability

If the spacer layer thickness is increased beyond conventional Ru single layer, then thermal stability and anti-intermixing improve, but device complexity increases

Engineering Contradiction:
Improvethermal stabilityVSAvoidspacer layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

Rather than simply increasing the thickness of a single Ru layer, the invention uses a composite alternating structure of Ru and x layers. This approach achieves enhanced thermal stability and reduced interlayer mixing through the composite configuration itself, avoiding the need for excessive thickness that would increase device complexity.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If conventional Ru single layer is used, then manufacturing is simpler, but interlayer mixing occurs during fabrication

Engineering Contradiction:
Improvespacer layer fabricationVSAvoidlayer composition stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The alternating Ru and x layers create a composite structure where the x layers (metal, oxide, or nitride) act as barriers that prevent interdiffusion and mixing between adjacent magnetic layers during fabrication processes. This composite configuration maintains compositional stability while remaining manufacturable through standard thin-film deposition techniques.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach maintains the stability of the spacer layer characteristics during thermal treatment, enhancing the strength of anti-ferromagnetic exchange coupling and improving the overall performance and reliability of the memory device.

Implementation Method 1

a spacer layer interposed between the first magnetic layer and the second magnetic layer, wherein the spacer layer includes a first layer, a second layer and an intermediate layer interposed between the first layer and the second layer... the first magnetic layer, the spacer layer and the second magnetic layer may form a synthetic anti-ferromagnet (SAF) structure

Methodology Applied
Scientific EffectAnti-ferromagnetic exchange coupling: Magnetism

Data Source

PatentUS10580969B2Electronic device
Publication Date: 2020.03.03 SK HYNIX INC
  • US10580969B2 patent drawing
  • US10580969B2 patent drawing
  • US10580969B2 patent drawing

AI summary

An electronic device may include a semiconductor memory, and the semiconductor memory may include a first magnetic layer; a second magnetic layer; and a spacer layer interposed between the first magnetic layer and the second magnetic layer, wherein the spacer layer includes a first layer, a second layer and an intermediate layer interposed between the first layer and the second layer, and wherein each of the first layer and the second layer includes an oxide, or a nitride, or a combination of an oxide and a nitride, the intermediate layer includes a multilayer structure including [Ru/x]n or [x/Ru]n, x includes a metal, an oxide, or a nitride, or a combination of a metal, an oxide and a nitride, and n represents an integer of 1 or greater.