Multi-Layered Dielectric Film for Microelectronic Devices

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Solution Overview

Problem

The reduction in cell capacitance of semiconductor devices due to smaller unit cell areas leads to increased power dissipation, reduced integration levels, and difficulties in low-voltage driving, necessitating a method to enhance capacitance per unit area without the limitations of materials with low dielectric constants like silicon oxide and silicon nitride.

Innovation Solution

A multi-layered dielectric film structure comprising a single component oxide layer with composite oxide layers on either side, where the single component oxide layer has a higher dielectric constant than the composite layers, and is made of materials such as tantalum oxide, with composite components like AlxHfyOz, formed without a layered structure to increase capacitance and reduce leakage current.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the unit cell area is reduced to increase integration level, then the integration level is improved, but the cell capacitance is reduced

Engineering Contradiction:
Improveintegration levelVSAvoidcell capacitance
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The patent changes the dielectric constant parameter of the capacitor dielectric layer from conventional materials (SiO2 with k=5, Si3N4 with k=10) to high-k dielectric materials (such as SrTiO3 with k>100, Pb(Zr,Ti)O3 with k>100). This parameter change enables achieving the required cell capacitance value even when the unit cell area is reduced, thus resolving the contradiction between integration level and cell capacitance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite dielectric structures combining high-k dielectric materials with conventional dielectric materials. For example, a structure with a high-k dielectric layer (SrTiO3 or Pb(Zr,Ti)O3) combined with SiO2 or Si3N4 layers is used. This composite approach optimizes both capacitance density and electrical characteristics, enabling high integration while maintaining required cell capacitance.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional dielectric materials (SiO2, Si3N4) are used, then the manufacturing process is simple, but the dielectric constant is low limiting capacitance increase

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoiddielectric constant
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The patent changes the dielectric constant parameter from conventional values (k=5 for SiO2, k=10 for Si3N4) to high-k values (k>100 for materials like SrTiO3 and Pb(Zr,Ti)O3). This parameter change enables achieving required capacitance values without increasing device area, while the manufacturing processes for these high-k materials have been adapted to existing semiconductor fabrication techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional dielectric materials with high-k dielectric materials, substituting materials with low dielectric constant (SiO2, Si3N4) with materials having high dielectric constant (SrTiO3, Pb(Zr,Ti)O3). This material substitution enables achieving the required capacitance density while maintaining compatibility with existing manufacturing processes through adapted deposition and processing techniques.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Quantity of substance

If high-k dielectric materials are used to increase capacitance, then the capacitance per unit area is improved, but the leakage current may increase

Engineering Contradiction:
Improvecapacitance per unit areaVSAvoidleakage current
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent employs composite dielectric structures where high-k dielectric materials (SrTiO3, Pb(Zr,Ti)O3) are combined with conventional dielectric materials (SiO2, Si3N4). The high-k layer provides high capacitance density, while the conventional dielectric layers serve as barrier layers that suppress leakage current. This composite structure resolves the contradiction between achieving high capacitance per unit area and maintaining low leakage current.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different material qualities to different regions of the dielectric structure. The high-k dielectric material is used in the region where high capacitance is needed, while conventional dielectric materials with lower leakage are used in regions where leakage suppression is critical. This local differentiation of material properties optimizes both capacitance and leakage characteristics.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layered dielectric film structure effectively increases capacitance per unit area, reduces power dissipation, and improves electrical characteristics, enabling higher integration and smaller chip sizes while maintaining reliability and leakage current performance.

Implementation Method 1

the dielectric property of the dielectric layer used in a capacitor can be evaluated by an equivalent oxide film thickness (known as a Toxeq value) and by a leakage current density. The equivalent oxide film thickness (Toxeq) is a value obtained by converting a thickness level of a dielectric film formed of a dielectric material other than a silicon oxide into an equivalent thickness level of a dielectric film made of a silicon oxide. As the Toxeq value is reduced, cell capacitance per unit area increases.

Methodology Applied
Scientific EffectDielectric permittivity: Dielectric Permittivity

Data Source

PatentUS7508649B2Multi-layered dielectric film of microelectronic device and method of manufacturing the same
Publication Date: 2009.03.24 SAMSUNG ELECTRONICS CO LTD
  • US7508649B2 patent drawing
  • US7508649B2 patent drawing
  • US7508649B2 patent drawing

AI summary

Multi-layered dielectric films which can improve the performance characteristics of a microelectronic device are provided as well as methods of manufacturing the same. The multi-layered dielectric film includes a single component oxide layer made of a single component oxide, and composite components oxide layers made of a composite components oxide including two or more different components formed along either side of the single component oxide layer without a layered structure.