Wide-band Multi-mode Optical Fiber Fluorine Doping Profile Control

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Solution Overview

Problem

Existing methods for manufacturing wide-band multi-mode optical fibers struggle to achieve consistent refractive index profiles and fluorine doping profiles, leading to significant variations in RMS pulse broadening across different wavelength ranges, which limits their operational bandwidth and bend sensitivity.

Innovation Solution

A method involving the deposition of germania-doped silica soot preforms, followed by fluorine doping in a furnace with controlled parameters such as doping temperature and partial pressure, to create co-doped core preforms with specific alpha profiles, ensuring a refractive index between 1.9 and 2.2 at 850 nm, and subsequent consolidation into sintered glass, while employing outside vapor deposition or vapor-phase axial deposition processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional fluorine doping methods are used during preform consolidation, then the doping process is simplified, but the refractive index profile control is poor and RMS pulse broadening varies significantly across wavelengths

Engineering Contradiction:
Improverefractive index profile consistencyVSAvoiddoping process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The doping process is segmented into two distinct stages: (1) Germania doping during soot deposition to establish the base refractive index gradient, and (2) Fluorine doping during preform consolidation to refine the profile and create the trench region. This segmentation allows independent optimization of each doping stage parameters, achieving precise refractive index control across different radial zones and wavelengths without excessive overall process complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The germania doping is performed as a preliminary action during the soot deposition phase before consolidation. This preliminary germania doping establishes the foundational refractive index gradient that will be subsequently modified by fluorine doping. By performing this action in advance, the patent achieves better overall profile control while maintaining a manageable two-stage process

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If single dopant (germania) profiling is used, then the manufacturing process is simple, but the operating bandwidth is limited and pulse broadening is high across wavelength ranges

Engineering Contradiction:
Improveoperating wavelength rangeVSAvoiddoping structure complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent employs composite doping by combining two different dopants (germania and fluorine) with distinct optical properties. Germania provides positive refractive index contribution for the core gradient, while fluorine provides negative contribution for profile refinement and trench creation. This composite approach enables the fiber to maintain low pulse broadening and achieve wide operating bandwidth across multiple wavelength ranges, overcoming the limitations of single-dopant designs

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

Different dopants are strategically distributed to different spatial zones: germania is concentrated in the core region to establish the primary gradient, while fluorine is introduced in specific zones including the trench region. This local differentiation of dopant quality and concentration allows optimization of light propagation characteristics across different radial positions and wavelength ranges, achieving versatile broadband performance

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If fluorine doping is performed at high concentrations, then the trench region formation is effective, but the refractive index profile control becomes difficult and manufacturing precision decreases

Engineering Contradiction:
Improverefractive index alpha profile controlVSAvoidfluorine dopant concentration
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The patent applies partial fluorine doping rather than uniform high-concentration doping throughout the preform. Fluorine is introduced at controlled concentrations specifically in regions where profile refinement is needed, such as the trench zone, while maintaining lower or zero fluorine content in the core. This partial action approach achieves effective trench formation and profile control without the manufacturing difficulties associated with uniform high-concentration fluorine doping

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in multi-mode optical fibers with reduced RMS pulse broadening variability across a wide wavelength range, achieving bandwidths greater than 2 GHz-km and low bend losses, thereby expanding the operating window and improving fiber performance.

Implementation Method 1

doping the germania-doped porous soot preform in a furnace with a fluorine dopant to form a co-doped soot preform

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

consolidating the co-doped soot preform to form a sintered glass, co-doped core preform

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS9964701B2Methods of manufacturing wide-band multi-mode optical fibers and core preforms for the same using specific fluorine doping parameter and 850 nm alpha profile
Publication Date: 2018.05.08 CORNING INC
  • US9964701B2 patent drawing
  • US9964701B2 patent drawing
  • US9964701B2 patent drawing

AI summary

A method of making a multi-mode optical fiber that includes: depositing a porous germania-doped silica soot to form a germania-doped porous soot preform; depositing a porous silica layer over the porous soot preform; doping the porous soot preform and the porous silica layer with a fluorine dopant to form a co-doped soot preform having a core region and a fluorine-doped trench region; consolidating the co-doped soot preform to form a sintered glass, co-doped core preform having a refractive index alpha profile between 1.9 and 2.2 measured at 850 nm; depositing a cladding comprising silica over the sintered glass, co-doped preform to form a multi-mode optical fiber preform; drawing the optical fiber preform into a multi-mode optical fiber. Further, the step of doping the germania-doped soot preform and the porous silica layer is conducted according to a doping parameter (Φ) that is set between 20 and 300, and given by:Φ=1×1014⁢Rprc2⁢exp⁡(-E/RTdop)⁢Tdop1/2x3/4.