Multi-Part Anode Extrusion Nozzle for High-Rate Cell Discharge

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Solution Overview

Problem

Current manufacturing techniques lack scalability for producing alkaline electrochemical cells with dual-anode configurations, which have shown improved high-rate discharge performance in small-scale tests, necessitating novel methods for large-scale production.

Innovation Solution

A method involving an extrusion nozzle with a hollow tubular body, lower deflector, and support rod to form anode portions with distinct characteristics within the electrochemical cell, allowing for the creation of a gradient anode structure by extruding anode material through an annular opening and a central conduit, enabling the formation of multiple anode portions with varying surfactant types and active material compositions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If multiple anode portions are positioned concentrically within the cell to improve high-rate discharge performance, then discharge performance is improved, but device complexity increases

Engineering Contradiction:
Improvehigh-rate discharge performanceVSAvoidanode configuration complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The anode is divided into multiple discrete anode portions (first anode portion, second anode portion, third anode portion) positioned concentrically within the cell. Each portion has distinct characteristics such as different surfactant types or active material compositions, allowing optimized discharge performance at different radial locations while maintaining manageable structural complexity through systematic arrangement

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different anode portions are assigned different local properties including varying surfactant concentrations, different active material compositions, or different porosity characteristics. This local differentiation enables each portion to optimize for specific discharge conditions, with inner portions handling high-rate discharge and outer portions providing additional capacity

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If a nozzle with support rod and deflector is used to extrude anode material, then manufacturing precision is improved, but device complexity increases

Engineering Contradiction:
Improveanode portion formation precisionVSAvoidnozzle structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The nozzle is divided into functional segments including a hollow tubular body for material delivery, a support rod for structural stability, and a deflector for shaping control. This segmentation allows each component to be optimized independently for its specific function while assembling into a cohesive precision tool

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The support rod acts as an intermediary structural element that maintains the integrity of the hollow tubular body during extrusion. The deflector serves as an intermediary shaping element that guides the anode material into the desired configuration, enabling precise formation without requiring overly complex nozzle designs

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances high-rate discharge performance by ensuring uniform discharge and reducing gassing, as the anode portions with lower charge transfer resistance near the current collector discharge first, preventing zinc oxide formation near the separator, thus maintaining active material availability and improving overall cell performance.

Implementation Method 1

A method involving an extrusion nozzle with a hollow tubular body, lower deflector, and support rod to form anode portions with distinct characteristics within the electrochemical cell, allowing for the creation of a gradient anode structure by extruding anode material through an annular opening and a central conduit

Methodology Applied
Scientific EffectExtrusion: Extrusion

Implementation Method 2

This approach enhances high-rate discharge performance by ensuring uniform discharge and reducing gassing, as the anode portions with lower charge transfer resistance near the current collector discharge first, preventing zinc oxide formation near the separator

Methodology Applied
Scientific EffectElectrochemical discharge: Redox Reactions

Data Source

PatentEP4094308B1Systems and methods for generating an electrochemical cell having a multi-part anode
Publication Date: 2023.11.22 ENERGIZER BRANDS LLC
  • EP4094308B1 patent drawingFigure 1
  • EP4094308B1 patent drawingFigure 2
  • EP4094308B1 patent drawingFigure 3A~3C

AI summary

A nozzle is provided for providing anode material into an electrochemical cell and method of using the same. The nozzle comprises a hollow tubular body extending between an open upper end and an open lower end; a lower deflector spaced apart from the open lower end of the hollow tubular body and forming an annular opening between a deflection surface of the lower deflector and the open lower end of the hollow tubular body; and a support rod connecting the lower deflector with the hollow tubular body, wherein the support rod is suspended within an interior of the hollow tubular body by one or more support trusses.