Multipass Spectroscopic Cell Optical Folding Prisms
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Solution Overview
Problem
Conventional multipass spectroscopic absorption cells face challenges in increasing path length without expanding the cell length, particularly due to imperfect mirror reflectivity, which limits sensitivity and complicates optical alignment, especially in the UV and visible spectra regions.
Innovation Solution
Incorporating an optical folding system with prisms that fold the principal optical axis by 180° or more, allowing for reduced cell length while maintaining or increasing path length, thereby enhancing sensitivity and structural strength, and reducing alignment issues.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Measurement precision
If the cell length is increased to increase the interaction path length, then the detection sensitivity is improved, but the structural strength and mechanical stability deteriorate
Solution Approach 1:
The patent applies dimensional transformation by folding the optical path using prisms arranged in a three-dimensional configuration. Instead of extending the cell length linearly in one dimension, the optical path is folded back on itself multiple times within a compact volume, effectively converting a one-dimensional path length problem into a three-dimensional spatial arrangement. This allows achieving long interaction paths (e.g., 100 meters) within a short physical cell length while maintaining structural integrity.
2Measurement precision
If the number of optical passes is increased to increase the interaction path length, then the detection sensitivity is improved, but the optical losses increase due to imperfect mirror reflectivity
Solution Approach 1:
The patent changes the optical parameters by using prisms instead of mirrors for folding the optical path. Prisms provide near-perfect reflection through total internal reflection, eliminating the reflectivity losses inherent in mirrored surfaces. This parameter change allows for a much higher number of optical passes (e.g., 500 passes) without significant optical loss, thereby increasing the interaction path length and detection sensitivity while minimizing energy loss.
3Measurement precision
If the number of optical passes is increased to increase the interaction path length, then the detection sensitivity is improved, but the optical alignment sensitivity increases
Solution Approach 1:
The patent introduces prisms as intermediary optical elements that mediate the folding of the optical path. These prisms provide fixed, stable reference surfaces for alignment and maintain consistent optical geometry throughout the multipass sequence. The prism interfaces are designed with precise angular relationships that reduce sensitivity to alignment errors, making the system easier to operate and maintain while allowing for a high number of optical passes.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This approach enables compact, portable, and more sensitive multipass spectroscopic absorption cells with increased interaction path lengths without increasing the number of passes or cell length, improving detection sensitivity and mechanical stability.
Implementation Method 1
an optical folding system located on the principal optical axis between the first and second reflectors, wherein said optical folding system comprises one or more prisms and is configured to fold the principal optical axis through an angle greater than 0°
Implementation Method 2
at least a first reflector and a second reflector that are configured to reflect a beam of light multiple times through the sample volume
Implementation Method 3
Optical absorption spectrometers are commonly used for gas phase absorption spectroscopy using the infrared, visible and ultraviolet parts of the optical spectrum
Data Source
AI summary
A multipass spectroscopic absorption cell comprises at least a first reflector (40) and a second reflector (42) that are configured to reflect a beam of light multiple times through a sample volume (V). At least one of the first and second reflectors (40,42) defines a principal optical axis (A) that extends through the sample volume (V). An optical folding system (52) is located on the principal optical axis (A) between the first and second reflectors, said optical folding system being configured to fold the principal optical axis (A) through an angle greater than 0°.


