Multiphase Polymer Coatings with Segregated Reactive Particles

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Solution Overview

Problem

Current coating technologies struggle to incorporate multiple reactive particles that cannot be mixed due to reactivity, limiting the development of multifunctional coatings with enhanced corrosion resistance and other applications, as existing methods fail to segregate these particles effectively during synthesis.

Innovation Solution

A multiphase polymer composition is developed, comprising chemically distinct polymer materials with microphase-separated domains, where solid functional particles are selectively dispersed and can react to environmental inputs such as UV light, temperature, or solvents, enabling the creation of coatings with enhanced corrosion resistance and other functional properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If multiple reactive particles are introduced into a single reaction vessel for coating synthesis, then the coating can potentially achieve multifunctionality, but the reactive particles interact and react with each other during synthesis, preventing effective segregation into distinct phases

Engineering Contradiction:
Improvemultifunctionality of coatingVSAvoidsegregation of reactive particles
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The patent divides the synthesis process into multiple separate reaction vessels, each containing different reactive particles. This segmentation prevents unwanted interactions between reactive particles during synthesis while allowing each particle type to be incorporated into the coating. The coating itself is divided into multiple phases, with each phase containing specific reactive particles segregated from others.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses a multi-phase polymer matrix as an intermediary medium to host different reactive particles. Each phase of the polymer matrix acts as a separate environment that can accommodate specific reactive particles without allowing them to interact directly. This intermediary structure enables multifunctionality while maintaining particle segregation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If reactive particles are kept separated in different reaction vessels during synthesis, then particle segregation is maintained, but the complexity of the manufacturing process increases

Engineering Contradiction:
Improvesegregation of reactive particlesVSAvoidsynthesis process complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent merges the separately synthesized multi-phase polymer materials into a single coating structure. After individual phases are synthesized in separate vessels with their respective reactive particles, these phases are combined to form the final multifunctional coating. This merging step consolidates the complexity of multiple synthesis operations into a unified product structure.

Inventive Principle:
Principle #5Merging (Combining)

3Ease of manufacture

If traditional single-vessel synthesis is used, then the manufacturing process is simpler, but reactive particles cannot be effectively segregated into specific phases

Engineering Contradiction:
Improvesynthesis process simplicityVSAvoidparticle phase segregation
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The synthesis process is segmented into multiple independent reaction vessels, each dedicated to synthesizing a specific phase of the polymer matrix with its associated reactive particles. This segmentation enables precise control over which particles end up in which phase, achieving manufacturing precision that cannot be obtained through simple single-vessel synthesis.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS11692109B2Multiphase coatings with separated functional particles, and methods of making and using the same
Publication Date: 2023.07.04 HRL LAB
  • US11692109B2 patent drawing
  • US11692109B2 patent drawing
  • US11692109B2 patent drawing

AI summary

Some variations provide a multiphase polymer composition comprising a first polymer material and a second polymer material that are chemically distinct, wherein the first polymer material and the second polymer material are microphase-separated on a microphase-separation length scale from about 0.1 microns to about 500 microns, wherein the multiphase polymer composition comprises first solid functional particles selectively dispersed within the first polymer material, and wherein the first solid functional particles are chemically distinct from the first polymer material and the second polymer material. Some embodiments provide an anti-corrosion composition comprising first corrosion-inhibitor particles or precursors selectively dispersed within the first polymer material, wherein the multiphase polymer composition optionally further comprises second corrosion-inhibitor particles or precursors selectively dispersed within the second polymer material. These multiphase polymer compositions may be used for other applications, such as self-cleaning, self-healing, or flame-retardant coatings. Methods of making and using these multiphase polymer compositions are disclosed.