Multi-Stage Bioscrubber for H2S Removal

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Solution Overview

Problem

Existing biological filtration systems using seashell media are inadequate for handling waste streams with significant hydrogen sulfide content, as they require larger media beds and slower flow rates, making them impractical for many wastewater treatment infrastructure sites.

Innovation Solution

A multi-stage treatment system comprising a first stage with foamed glass aggregate media and a second stage with shell media, utilizing specific bacteria species and irrigation systems to recirculate fluids, effectively removing hydrogen sulfide and other contaminants from air streams.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If single-stage shell media biofiltration is used, then biological treatment is achieved, but the system requires larger media beds and slower flow rates for waste streams with significant hydrogen sulfide content

Engineering Contradiction:
Improvehydrogen sulfide removal efficiencyVSAvoidmedia bed volume
Core Design Contradiction:
ReliabilityVSVolume of stationary object

Solution Approach 1:

The treatment system is divided into two distinct stages: a first stage using foamed glass aggregate media for hydrogen sulfide removal, and a second stage using shell media for ammonia and other contaminant removal. This segmentation allows each stage to be optimized for its specific function, enabling the first stage to handle high hydrogen sulfide loads without requiring excessively large media beds, while the second stage focuses on ammonia removal where shell media excels.

Inventive Principle:
Principle #1Segmentation

2Reliability

If single-stage shell media biofiltration is used, then biological treatment is achieved, but the system requires slower flow rates making it impractical for many sites

Engineering Contradiction:
Improvecontaminant removal efficiencyVSAvoidair flow rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

By dividing the treatment into two stages with different media types, the system can accommodate higher overall air flow rates. The first stage with foamed glass aggregate is optimized for hydrogen sulfide removal at higher flow rates, while the second stage with shell media handles ammonia removal, allowing the system to maintain effective treatment without the severe flow rate limitations of a single-stage shell media system.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each stage is designed with media and operating conditions locally optimized for its specific contaminant removal function. The first stage uses foamed glass aggregate with characteristics suited for hydrogen sulfide absorption, while the second stage uses shell media with properties optimized for ammonia removal. This local optimization allows each stage to operate at appropriate flow rates for its specific function.

Inventive Principle:
Principle #3Local quality

3Reliability

If single-stage shell media biofiltration is used, then treatment is achieved, but the footprint of the system becomes too large for many wastewater treatment infrastructure sites

Engineering Contradiction:
Improvecontaminant removal efficiencyVSAvoidsystem footprint
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The two-stage system with specialized media in each stage achieves effective contaminant removal with a more compact configuration. By dividing the treatment function between two smaller, specialized stages rather than one large general-purpose stage, the overall system footprint is reduced while maintaining or improving removal efficiency for both hydrogen sulfide and ammonia.

Inventive Principle:
Principle #1Segmentation

4Reliability

If single-stage shell media biofiltration is used, then treatment is achieved, but the shell media life is reduced due to disproportionate effect of hydrogen sulfide

Engineering Contradiction:
Improvetreatment effectivenessVSAvoidshell media service life
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

By separating hydrogen sulfide removal into the first stage using foamed glass aggregate media, the shell media in the second stage is protected from disproportionate exposure to hydrogen sulfide. This segmentation extends the service life of the shell media by assigning it primarily to ammonia removal where it can function more effectively and last longer, while the foamed glass aggregate absorbs the brunt of hydrogen sulfide treatment.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves high removal efficiencies for hydrogen sulfide (up to 99%) and ammonia (up to 98%), reducing the overall footprint of the treatment system and extending the life of shell media, while maintaining cost-effectiveness compared to single-stage systems.

Implementation Method 1

The shells provide a substrate for microorganisms that absorb contaminants in the air stream

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

microorganisms that absorb contaminants in the air stream

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 3

an irrigation system configured to recirculate irrigation fluid from a bottom drain area to irrigation outlets above the foamed glass aggregate media

Methodology Applied
Scientific EffectRecirculation:

Implementation Method 4

a negative pressure source communicating with the second stage outlet to draw air through the first and second stage vessels

Methodology Applied
Scientific EffectNegative pressure flow: Pressure Gradient

Implementation Method 5

Seashells contain high levels of CaCO3, which neutralize the acid byproducts of oxidation

Methodology Applied
Scientific EffectChemical neutralization: Chemical Bonding

Data Source

PatentUS11351501B2Multi-stage treatment system and methods for removal of target vapor compounds from contaminated air streams
Publication Date: 2022.06.07 ANUA INTERNATIONAL LLC
  • US11351501B2 patent drawing
  • US11351501B2 patent drawing
  • US11351501B2 patent drawing

AI summary

A multi-stage treatment system for removal of target vapor compounds from a contaminated air stream consisting of an initial bioscrubber stage utilizing a plurality of filter media derived from foamed glass immediately followed by a biofilter stage utilizing a plurality of media derived from the calcareous exoskeleton of a bivalve mollusk (shell media).