Multistage Polymer Cosmetic Formulation for Wear and Color Retention

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Solution Overview

Problem

There is a need for color cosmetic formulations that provide effective wear resistance with color retention, as existing formulations struggle to maintain long-lasting application without the need for refreshing or touching up.

Innovation Solution

A personal care formulation comprising a multistage polymer with an acrylate rich stage and a carbosiloxane rich stage, where the acrylate rich stage includes structural units of monoethylenically unsaturated non-ionic alkyl (meth)acrylates and carbosiloxane monomers, and the carbosiloxane rich stage includes vinyl monomers, to enhance wear resistance and color retention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional cosmetic formulations are used, then application is simple and quick, but wear resistance and color retention are insufficient requiring refreshing or touching up

Engineering Contradiction:
Improvewear resistanceVSAvoidformulation complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent employs a multistage polymer comprising an acrylate-rich stage and a carbosiloxane-rich stage as a composite material system. The acrylate-rich stage provides adhesion and film formation, while the carbosiloxane-rich stage provides water resistance and wear properties. This composite polymer structure resolves the contradiction by integrating multiple functional materials into a single formulation that achieves both long wear resistance and color retention without requiring complex multi-component systems or frequent reapplication.

Inventive Principle:
Principle #40Composite materials

2Reliability

If multistage polymer with acrylate rich stage and carbosiloxane rich stage is used, then wear resistance and color retention are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecolor retentionVSAvoidpolymer synthesis complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies segmentation by dividing the polymer synthesis into two distinct stages: an acrylate-rich stage and a carbosiloxane-rich stage. Each stage can be synthesized and characterized independently, allowing for controlled composition ratios (acrylate-rich stage: 40-80 wt%, carbosiloxane-rich stage: 20-60 wt%). This segmentation simplifies manufacturing by enabling modular synthesis procedures and quality control, while still achieving the desired color retention and wear resistance properties through the coordinated action of both stages.

Inventive Principle:
Principle #1Segmentation

Data Source

PatentUS12370134B2Personal care formulation
Publication Date: 2025.07.29 ROHM & HAAS CO
  • US12370134B2 patent drawing
  • US12370134B2 patent drawing
  • US12370134B2 patent drawing

AI summary

Personal care formulation is provided having multistage polymer, comprising: acrylate rich stage comprising: (a) structural units of monomer selected from C1-22 alkyl (meth)acrylates and structural units of first carbosiloxane monomer of formula (I); and (b) carbosiloxane rich stage, comprising: structural units of second carbosiloxane monomer of formula (I); wherein a is 0 to 3; wherein d is 0 or 1; wherein R1 is selected from hydrogen, C1-10 alkyl group and aryl group; wherein R2 is selected from hydrogen and C1-10 alkyl group; wherein R8 is —O—Si(CH3)3 group; wherein Y is selected from formula (II), (III) and (IV); wherein R4 and R6 are selected from hydrogen and methyl group; wherein R3 and R5 are C1-10 alkylene group; wherein R7 is C1-10 alkyl group; wherein b is 0 to 4 and wherein c is 0 or 1; and wherein the first and second carbosiloxane monomer of formula (I) are same or different.