Multivalent D-peptide Polymers for A-beta Oligomer Binding

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Solution Overview

Problem

Current treatments for Alzheimer's disease are unable to prevent or cure the condition, as they fail to effectively target and reduce toxic A-beta oligomers and fibrils, which are responsible for the progression of the disease, and there is a lack of diagnostic tools for early detection before symptoms appear.

Innovation Solution

Development of multivalent amyloid-beta-binding polymeric substances composed of D-amino acids that specifically bind to A-beta oligomers with high affinity, preventing their reproduction and destruction, and serving as probes for early diagnosis.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If monovalent A-beta ligands are used, then the affinity for A-beta oligomers is limited, but the complexity of the substance is low

Engineering Contradiction:
Improvebinding affinityVSAvoidmolecular complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple A-beta binding ligands into a single multivalent polymer structure. The polymer contains multiple binding sites that can simultaneously interact with A-beta oligomers, thereby increasing the overall binding affinity and effectiveness compared to monovalent ligands while maintaining a manageable molecular structure through systematic design.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates composite polymeric structures that integrate multiple binding motifs within a single molecule. These composite structures combine the advantages of different ligand designs and achieve enhanced binding properties that exceed the sum of individual monovalent ligands, resolving the contradiction between affinity and complexity.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If existing drugs are used, then some symptoms are alleviated, but the disease progression cannot be slowed or cured

Engineering Contradiction:
Improvesymptom reliefVSAvoiddisease modification
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent designs ligands that specifically copy and bind to the structure of toxic A-beta oligomers. By creating molecules that mimic the oligomer structure, the multivalent polymers can selectively recognize and bind to these toxic forms with high affinity, enabling both symptom relief and potential disease modification through targeted intervention.

Inventive Principle:
Principle #26Copying

Solution Approach 2:

The invention changes the binding parameters by using multivalent structures with multiple interaction sites. This increases the binding strength and specificity for A-beta oligomers compared to monovalent ligands, transforming the interaction from weak and non-specific to strong and selective, thereby achieving both symptomatic relief and disease-modifying effects.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If A-beta monomer concentration is reduced, then oligomer formation is prevented, but the effect is insufficient for treating established disease

Engineering Contradiction:
Improveprevention effectivenessVSAvoidbinding capacity
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent employs multivalent ligands that can bind to A-beta oligomers before they undergo prion-like multiplication and form larger aggregates. By acting early in the oligomer stage with high-affinity multivalent binding, the ligands prevent the exponential amplification of toxic species, achieving effective prevention and treatment with manageable ligand concentrations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The multivalent polymers act as intermediary molecules that bridge and stabilize A-beta oligomers in a non-toxic bound state. This intermediary binding prevents the oligomers from interacting with cellular targets and propagating, effectively neutralizing their toxicity while maintaining a manageable concentration of therapeutic agent.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These polymers effectively bind to A-beta oligomers, reducing their formation and multiplication, and can be used for early diagnosis and treatment of Alzheimer's disease, offering a potential cure and diagnostic tool.

Implementation Method 1

The polymers according to the invention bind both the small, freely diffusible A-beta oligomers and larger A-beta oligomers through to fibrils

Methodology Applied
Scientific EffectMolecular recognition and binding:

Implementation Method 2

The polymers constructed according to the invention from monomers which in turn bind to A-beta oligomers show clear, synergetic effects with regard to their selectivity and affinity for the A-beta oligomers

Methodology Applied
Scientific EffectMultivalent binding:

Data Source

PatentEP2834644B1Polymers containing multivalent amyloid-beta-binding d-peptides and their use
Publication Date: 2019.08.21 FORSCHUNGSZENTRUM JULICH GMBH
  • EP2834644B1 patent drawingFigure 1
  • EP2834644B1 patent drawingFigure 2
  • EP2834644B1 patent drawingFigure 3

AI summary

The invention relates to novel multivalent amyloid-beta-binding polymeric substances consisting of a plurality of substances joined together which per se already have amyloid-beta-binding properties, and the use of these substances, called "polymers" hereinbelow, especially in medicine.