MXene-Encapsulated Post-Transition Metal Composites

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Solution Overview

Problem

There is a need for new composites containing MXenes and facile methods for producing such composites that effectively combine MXenes with post-transition metals and ceramics, addressing the limitations of existing production techniques.

Innovation Solution

A composite comprising MXenes and post-transition metals or ceramics, where the MXene encapsulates the post-transition metal, and a method involving dispersion in organic and aqueous carriers, followed by mixing and separation to form a solid precipitate, optimizing the encapsulation and distribution of MXene layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If conventional composite production techniques are used, then existing composites can be manufactured, but they fail to effectively combine MXenes with post-transition metals and ceramics

Engineering Contradiction:
Improveability to combine MXenes with post-transition metals and ceramicsVSAvoidproduction technique effectiveness
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent uses an organic carrier (such as ethanol or toluene) as an intermediary medium to disperse post-transition metal particles before combining with MXene aqueous dispersion. This intermediary carrier enables effective combination of MXenes with post-transition metals by providing a compatible dispersion medium that facilitates uniform distribution and subsequent encapsulation, resolving the incompatibility issue of conventional techniques

Inventive Principle:
Principle #24Intermediary (Mediator)

2Strength

If MXene encapsulation of post-transition metals is achieved, then mechanical properties are enhanced, but production complexity increases

Engineering Contradiction:
ImproveVickers microhardness and fracture toughnessVSAvoidproduction process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent performs preliminary dispersion of post-transition metals in organic carriers before combining with MXene aqueous dispersions. This preliminary action ensures uniform distribution of metal particles and proper encapsulation by MXene layers, achieving enhanced mechanical properties through controlled encapsulation while maintaining a relatively simple two-stage process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent creates a composite structure where MXene layers encapsulate post-transition metal particles, forming a core-shell composite material. This composite approach combines the advantageous properties of both MXenes (high strength, flexibility) and post-transition metals (conductivity, mechanical strength), achieving superior mechanical properties through material composition rather than complex processing

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If dispersal in organic and aqueous carriers is used, then uniform distribution is achieved, but separation and collection become more challenging

Engineering Contradiction:
Improveuniform distribution of MXene layersVSAvoidseparation and collection difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent separates the dispersion and collection stages by first creating uniform dispersions in compatible carriers, then allowing natural sedimentation or simple filtration to separate the solid precipitate from the liquid carrier. This extraction approach achieves uniform distribution during dispersion while simplifying separation through phase differentiation, avoiding complex separation equipment

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting composite exhibits enhanced mechanical properties, including Vickers microhardness and fracture toughness, and the method allows for scalable production of MXene-based metal and ceramic composites with improved structural integrity.

Implementation Method 1

dispersing the post-transition metal in an organic carrier, thereby forming a first dispersion

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

dispersing the MXene in an aqueous carrier, thereby forming a second dispersion

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 3

mixing the first dispersion and the second dispersion, thereby forming a liquid phase and a solid precipitate comprising the composite

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 4

allowing the solid precipitate to settle for from 30 seconds to 2 minutes

Methodology Applied
Scientific EffectSedimentation: Sedimentation

Implementation Method 5

the collecting comprises at least partially separating the liquid phase from the solid precipitate

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Data Source

PatentUS20230174787A1Mxenes-metal and ceramic assemblies and composites
Publication Date: 2023.06.08 THE TRUSTEES OF INDIANA UNIV
  • US20230174787A1 patent drawing
  • US20230174787A1 patent drawing
  • US20230174787A1 patent drawing

AI summary

A composite comprising a MXene and a post-transition metal wherein the post-transition metal is at least partially encapsulated by from 1 to 4 layers of the MXene. Methods of making such a composite are also disclosed.