Vertical NAND Charge Trap Layer With Nanocrystals for Charge Retention

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Solution Overview

Problem

In vertical NAND flash memory devices, the increase in stacked memory cells and decrease in cell height lead to lateral charge spreading, deteriorating charge retention due to charge movement between cells, which affects memory density and reliability.

Innovation Solution

A vertical NAND flash memory device is developed with a charge trap layer comprising amorphous metal oxynitride and spatially discrete nitride nanocrystals, which improves retention by minimizing charge movement through increased trap energy and density, and by inserting specific nitride/oxide layers to inhibit crystallization and enhance dielectric constant and capacitance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the number of stacked memory cells is increased and cell height is decreased to improve memory density, then memory integration is improved, but lateral charge spreading occurs and charge retention deteriorates

Engineering Contradiction:
Improvememory densityVSAvoidcharge retention
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The charge trap layer is designed with spatially discrete nanocrystals distributed within an amorphous metal oxynitride matrix, creating localized charge trapping sites with different properties from the surrounding matrix. This local quality differentiation allows charges to be confined at specific nanocrystal locations while the amorphous matrix provides overall structural stability and prevents lateral charge spreading between adjacent memory cells.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The charge trap layer employs a composite structure combining amorphous metal oxynitride material with dispersed nanocrystals. This composite material integrates the benefits of both components: the amorphous metal oxynitride provides a stable matrix with appropriate dielectric properties, while the embedded nanocrystals create discrete charge trapping centers that enhance charge retention without causing lateral charge spreading.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If a conventional charge trap layer structure is used, then manufacturing is simpler, but charge movement between cells occurs and retention is poor

Engineering Contradiction:
Improvecharge trap layer fabricationVSAvoidcharge retention
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The charge trap layer utilizes changes in material parameters by employing amorphous metal oxynitride with specific compositional ratios and incorporating nanocrystals of controlled size and distribution. These parameter changes create a charge trap layer with optimized electrical properties that prevent charge movement between cells while maintaining manufacturability through established thin film deposition and heat treatment processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively improves charge retention and memory window characteristics by suppressing charge movement, enhancing the reliability and operating characteristics of the vertical NAND flash memory device.

Implementation Method 1

a charge trap layer which includes: a matrix; and a plurality of nanocrystals which are provided in the matrix, the plurality of nanocrystals including nitride

Methodology Applied
Scientific EffectQuantum confinement:

Implementation Method 2

a matrix including amorphous metal oxynitride

Methodology Applied
Scientific EffectDielectric permittivity: Dielectric Permittivity

Implementation Method 3

during subsequent heat treatment, the added nitrogen/oxide layers inhibit crystallization of the existing charge trap layer, resulting in the formation of an amorphous thin film

Methodology Applied
Scientific EffectCrystallization: Crystallisation

Data Source

PatentEP4489545A1Vertical NAND flash memory device and electronic apparatus including the same
Publication Date: 2025.01.08 SAMSUNG ELECTRONICS CO LTD
  • EP4489545A1 patent drawingFigure 1
  • EP4489545A1 patent drawingFigure 2
  • EP4489545A1 patent drawingFigure 3

AI summary

A vertical NAND flash memory device and an electronic apparatus including the same are provided. The vertical NAND flash memory device includes a plurality of cell arrays. Each of the plurality of cell arrays includes a channel layer, a charge trap layer, and a plurality of gate electrodes provided on the charge trap layer. The charge trap layer includes a matrix including amorphous metal oxynitride and nanocrystals dispersed in the matrix and including nitride having semiconductor characteristics.