Nano-structured Anode Composition for Lithium Metal Batteries

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Solution Overview

Problem

Lithium metal batteries face challenges with dendrite formation leading to internal short circuits and thermal runaway, which have hindered their commercialization for electric vehicles and microelectronic devices due to complex, costly, or laborious solutions in existing approaches.

Innovation Solution

A nano-structured anode composition featuring interconnected conductive nano-filaments with a lithium foil, providing a stable and cost-effective solution that prevents dendrite formation and enhances cycling stability, allowing for high specific capacity and energy density.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If lithium metal is used as anode material to achieve high specific capacity, then energy density is improved, but dendrite formation occurs leading to internal short circuits and thermal runaway

Engineering Contradiction:
Improvespecific capacityVSAvoidsafety
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent applies local quality by creating a non-uniform lithium distribution pattern through controlled deposition on the anode surface. The lithium is deposited in a dispersed manner rather than uniform coating, creating local variations in lithium concentration that prevent dendrite formation while maintaining high overall capacity. This localized control of lithium distribution resolves the contradiction between high capacity and safety.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs preliminary action by pre-depositing lithium on the anode surface before battery operation begins. This initial lithium layer serves as a buffer that controls subsequent lithium deposition patterns during cycling, preventing dendrite formation from the outset. The preliminary lithium deposition establishes a safe operating pattern that maintains both high capacity and safety throughout battery life.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If conventional methods are used to prevent dendrite formation, then safety is improved, but device complexity and manufacturing cost increase

Engineering Contradiction:
Improvedendrite preventionVSAvoidanode structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the dendrite prevention function from complex multi-component systems and implements it through a simple controlled lithium deposition process. By removing unnecessary separator modifications, coating layers, and complex structures, the invention achieves dendrite prevention through essential lithium deposition control alone, significantly reducing device complexity while maintaining safety.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent applies self-service by enabling the lithium deposition process to automatically regulate its own pattern without external control mechanisms. The controlled deposition method creates a self-organizing lithium distribution that inherently prevents dendrite formation through the physical chemistry of the deposition process itself, eliminating the need for complex active control systems or monitoring devices.

Inventive Principle:
Principle #25Self-service

3Productivity

If lithium foil is used directly as anode to achieve high energy density, then productivity is improved, but manufacturing precision and control over lithium distribution deteriorate

Engineering Contradiction:
Improveenergy densityVSAvoidlithium distribution uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by pre-depositing lithium on the anode surface in a controlled pattern before battery assembly. This preliminary deposition establishes the desired lithium distribution uniformity at the manufacturing stage, ensuring consistent performance across all batteries while maintaining high energy density. The pre-established pattern prevents later variations in lithium distribution during operation.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nano-structured anode composition achieves exceptional cycling stability and high specific capacity, preventing dendrite formation and extending cycle life, thus addressing the safety and efficiency concerns in lithium metal and lithium-air batteries.

Implementation Method 1

an integrated three-dimensional network structure of electrically conductive nanometer-scaled filaments

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

interconnected to form a porous network of electron-conducting paths comprising interconnected pores

Methodology Applied
Scientific EffectIon transport: Diffusion

Data Source

PatentUS8962188B2Anode compositions for lithium secondary batteries
Publication Date: 2015.02.24 HONEYCOMB BATTERY CO
  • US8962188B2 patent drawing
  • US8962188B2 patent drawing
  • US8962188B2 patent drawing

AI summary

A lithium secondary battery comprising a cathode, an anode, and a separator-electrolyte assembly or electrolyte layer disposed between the cathode and the anode, wherein the anode comprises: (a) an integrated nano-structure of electrically conductive nanometer-scaled filaments that are interconnected to form a porous network of electron-conducting paths comprising interconnected pores, wherein the filaments have a transverse dimension less than 500 nm; and (b) a foil of lithium or lithium alloy as an anode active material. The battery exhibits an exceptionally high specific capacity, an excellent reversible capacity, and a long cycle life.